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Merck
CN

157902

1,3-二溴-5,5-二甲基海因

98%

别名:

1,3-二溴-5,5-二甲基乙内酰脲

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关于此项目

经验公式(希尔记法):
C5H6Br2N2O2
化学文摘社编号:
分子量:
285.92
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-030-9
Beilstein/REAXYS Number:
146024
MDL number:
Assay:
98%
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InChI key

VRLDVERQJMEPIF-UHFFFAOYSA-N

InChI

1S/C5H6Br2N2O2/c1-5(2)3(10)8(6)4(11)9(5)7/h1-2H3

SMILES string

CC1(C)N(Br)C(=O)N(Br)C1=O

assay

98%

mp

197-199 °C (dec.) (lit.)

Quality Level

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Application

用于烷氧基苯甲酸的芳香溴化以及烯烃的溴氟化。

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 3 - Skin Corr. 1B - Skin Sens. 1

存储类别

5.1B - Oxidizing hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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M Hilp
Die Pharmazie, 57(1), 45-48 (2002-02-12)
PH. EUR. 2002 uses elemental bromine performing iron limit tests for maleic acid (iron 5 ppm) and titanium dioxide (iron 200 ppm). 1,3-Dibromo-5,5-dimethylhydantoin (DBH) can replace bromine water. For the iron limit test of maleic acid bivalent iron is oxidized
M Hilp
Die Pharmazie, 56(7), 548-551 (2001-08-08)
The identification of lactate according to Ph. Eur. 1997 and DAB 2000 uses the oxidation of lactic acid to pyruvic acid by boiling with bromine water in sulphuric acid. Acetaldehyde arising by decarboxylation is detected according to Legal applying a
Tetrahedron Letters, 34, 931-931 (1993)
M Hilp
Die Pharmazie, 57(4), 250-251 (2002-05-10)
PH. EUR. 2002 identifies nicotinamid, nicotinic acid, and nikethamide according the reaction of König using cyanogen bromide solution prepared with bromine water and ammonium thiocyanate immediately before use. This colour reaction can be better performed with 1,3-dibromo-5,5-dimethylhydantoin (DBH) and sulphanilic
Gloria Hernández-Torres et al.
Organic letters, 14(7), 1858-1861 (2012-03-27)
Organocatalytic stereospecific dibromination of a wide variety of functionalized alkenes was achieved using a stable, inexpensive halogen source, 1,3-dibromo 5,5-dimethylhydantoin, and a simple thiourea catalyst at room temperature. The presence of a tertiary amine enhanced the rate of the dibromination

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