产品名称
二氯磷酸甲酯, 85%
InChI key
SNVCRNWSNUUGEA-UHFFFAOYSA-N
InChI
1S/CH3Cl2O2P/c1-5-6(2,3)4/h1H3
SMILES string
COP(Cl)(Cl)=O
assay
85%
refractive index
n20/D 1.436 (lit.)
bp
62-64 °C/15 mmHg (lit.)
density
1.488 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
Analysis Note
可能含有甲醇杂质
Application
Methyl dichlorophosphate was used in the synthesis of:
- 4,6-cyclic phosphate tetrasaccharide
- 8-(2′′-hydroxyethoxy)adenosine-5′,2′′-phosphate derivative
- analogs of (R)-1-O-hexadecyl-2-palmitoyl-sn-glycero-3-phosphoethanolamine poly(ethylene glycol)
- dioxaphosphorino[m,n-x]pyridines compounds
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Dominika Turek et al.
Organic & biomolecular chemistry, 4(7), 1236-1241 (2006-03-25)
A spacer-equipped tetrasaccharide, p-aminocyclohexylethyl alpha-l-Colp-(1-->2)-beta-d-Galp-(1-->3)-[alpha-l-Colp-(1-->4)]-beta-D-GlcpNAc, containing a 4,6-cyclic phosphate in the galactose residue, has been synthesised. The structure corresponds to a part of the repeating unit of the capsular (and lipo-) polysaccharide of the endemic bacteria Vibrio cholerae type O139
Syntheses of Ortho-Hydroxymethylpyridinols and Dioxaphosphorino [m, nx] pyridines.
Leroy F, et al.
Synthetic Communications, 26(12), 2257-2272 (1996)
Thomas L Andresen et al.
Journal of medicinal chemistry, 47(7), 1694-1703 (2004-03-19)
An enzymatically activated liposome-based drug-delivery concept involving masked antitumor ether lipids (AELs) has been investigated. This concept takes advantage of the cytotoxic properties of AEL drugs as well as the membrane permeability enhancing properties of these molecules, which can lead
T Maruyama et al.
Nucleic acids symposium series, (17)(17), 61-63 (1986-01-01)
Reaction of 8-bromo-2',3'-O-isopropylidene-5'-O-(tetrahydropyran-2-yl) adenosine (Ib) with lithium 2-(tetrahydropyran-2-yloxy) ethoxide, followed by removal of the tetrahydropyran-2-yl groups, afforded 8-(2''-hydroxyethoxy)-2',3'-O-isopropylideneadenosine (II). Successive treatment of II with n-butyllithium and with methyl dichlorophosphate provided the 5',2''-(methyl phosphate) derivative (IIIa and IIIb).
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