Merck
CN

158623

Sigma-Aldrich

苯氧乙酰氯

98%

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线性分子式:
C6H5OCH2COCl
CAS号:
分子量:
170.59
Beilstein:
607585
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

98%

折射率

n20/D 1.534 (lit.)

bp

225-226 °C (lit.)

密度

1.235 g/mL at 25 °C (lit.)

SMILES string

ClC(=O)COc1ccccc1

InChI

1S/C8H7ClO2/c9-8(10)6-11-7-4-2-1-3-5-7/h1-5H,6H2

InChI key

PKUPAJQAJXVUEK-UHFFFAOYSA-N

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此商品
251313157147B2753
Phenoxyacetyl chloride 98%

Sigma-Aldrich

158623

苯氧乙酰氯

Pimeloyl chloride 98%

Sigma-Aldrich

251313

1,7-庚二酰氯

Valeroyl chloride 98%

Sigma-Aldrich

157147

戊酰氯

Butyrylcholine chloride ≥98%

Sigma-Aldrich

B2753

氯化丁酰胆碱

refractive index

n20/D 1.534 (lit.)

refractive index

n20/D 1.469 (lit.)

refractive index

n20/D 1.42 (lit.)

refractive index

-

bp

225-226 °C (lit.)

bp

113 °C/5 mmHg (lit.)

bp

125-127 °C (lit.)

bp

-

density

1.235 g/mL at 25 °C (lit.)

density

1.205 g/mL at 25 °C (lit.)

density

1.016 g/mL at 25 °C (lit.)

density

-

应用

Phenoxyacetyl chloride was used in the synthesis of:
  • series of macrocyclic bis-β-lactams
  • 5-phenyl-6-epiphenoxymethylpenicillin benzyl ester
  • N-protected guanosine derivatives, useful in RNA synthesis
  • phenyloxyketene, for cycloaddition to imines leading to β-lactams

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B - STOT SE 3

靶器官

Respiratory system

补充剂危害

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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丙酰氯

Natarajan Arumugam et al.
Medicinal chemistry (Shariqah (United Arab Emirates)), 10(7), 730-737 (2014-02-27)
A series of macrocyclic bis-β-lactams has been synthesized in three good yielding steps using a Staudinger [2+2] cycloaddition reaction of ketene derived from phenoxyacetyl chloride as the key step. The reaction provided a diastereomeric mixture of cis-anti-cis (C2-symmetry) and cis-syn-cis
H Vanderhaeghe et al.
Journal of medicinal chemistry, 18(5), 486-490 (1975-05-01)
Cycloaddition of azidoacetyl chloride to benzyl D-5,5-dimethyl-5-phenyl-2-thiazoline-4-carboxylate (1a) gave 5-phenyl-6alpha-azidopenicillanate (2a). By catalytic reduction of 2a and reaction with phenoxyacetyl chloride, 5-phenyl-6-epiphenoxymethylpenicillin benzyl ester (4a) was obtained. Oxidation of 4a gave the sulfoxide 6, which was isomerized in the presence
Tetrahedron, 63, 3380-3380 (2007)
Tetrahedron Letters, 48, 1657-1657 (2007)
Yupeng Fan et al.
Organic letters, 6(15), 2555-2557 (2004-07-17)
[reaction: see text] The formation of a guanosine derivative silylated at both the O6 and amino groups was identified by (15)N NMR. This intermediate allows facile reaction with acetyl chloride or phenoxyacetyl chloride to give in high yield the corresponding

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