160385
酞酰亚胺 钾盐
98%
别名:
邻苯二甲酰亚胺 钾盐, 酞酰亚胺钾
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关于此项目
经验公式（希尔记法）:
C8H4KNO2
化学文摘社编号:
分子量:
185.22
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
214-046-6
Beilstein/REAXYS Number:
3598719
MDL number:
产品名称
酞酰亚胺 钾盐, 98%
InChI key
FYRHIOVKTDQVFC-UHFFFAOYSA-M
InChI
1S/C8H5NO2.K/c10-7-5-3-1-2-4-6(5)8(11)9-7;/h1-4H,(H,9,10,11);/q;+1/p-1
SMILES string
[K]N1C(=O)c2ccccc2C1=O
assay
98%
form
powder
mp
>300 °C (lit.)
solubility
water: soluble 50 mg/mL, clear to slightly hazy, colorless to yellow
functional group
imide
Quality Level
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Application
邻苯二甲酰亚胺钾盐被用作一种有机催化剂，用于在极其温和的条件下对各种羰基化合物进行氰基甲硅烷基化。它还被用于将烯丙基-和烷基卤化物转化为受保护的伯胺。
酞酰亚胺钾与有机卤化物在二甲基甲酰胺中的缩合反应已有报告。邻苯二酰亚胺钾与一氯化硫在石油醚中的反应已被研究。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
346.3 °F - closed cup
flash_point_c
174.6 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
Tetrahedron Letters, 48, 3043-3043 (2007)
An improved procedure for the condensation of potassium phthalimide with organic halides.
Sheehan JC and Bolhofer WA.
Journal of the American Chemical Society, 72(6), 2786-2788 (1950)
Reactions of Phthalimide and Potassium Phthalimide with Sulfur Monochloride.
Kalnins MV.
Canadian Journal of Chemistry, 44(17), 2111-2113 (1966)
Palladium-catalyzed direct functionalization of imidazolinone: synthesis of dibromophakellstatin.
Jianming Lu et al.
Journal of the American Chemical Society, 129(25), 7768-7769 (2007-06-02)
Activation of trimethylsilyl cyanide by potassium phthalimide for facile synthesis of TMS-protected cyanohydrins.
Dekamin MG and Karimi Z.
Journal of Organometallic Chemistry, 694(12), 1789-1794 (2009)
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