160474
2-溴噻唑
98%
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关于此项目
经验公式（希尔记法）:
C3H2BrNS
化学文摘社编号:
分子量:
164.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-229-4
Beilstein/REAXYS Number:
105724
MDL number:
Assay:
98%
Form:
liquid
InChI key
RXNZFHIEDZEUQM-UHFFFAOYSA-N
InChI
1S/C3H2BrNS/c4-3-5-1-2-6-3/h1-2H
SMILES string
Brc1nccs1
assay
98%
form
liquid
refractive index
n20/D 1.593 (lit.)
bp
171 °C (lit.)
density
1.82 g/mL at 25 °C (lit.)
functional group
bromo
storage temp.
2-8°C
Quality Level
Application
2-溴噻唑用于 N -芳基-5-和 7-氮杂吲哚。2-溴噻唑也用作合成的起始试剂：
- 2-氰基噻唑（cpper 催化氰化）
- 2,4,5-三取代噻唑
- 新型缺电子稠合吡咯 [3,2- d :4,5- d ′] 双噻唑
- 3-吲哚
存储类别
12 - Non Combustible Liquids
wgk
WGK 3
flash_point_f
closed cup - does not flash
flash_point_c
closed cup - does not flash
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
Synlett, 555-555 (2007)
Tetrahedron Letters, 48, 4831-4831 (2007)
Cora Dunst et al.
The Journal of organic chemistry, 76(16), 6972-6978 (2011-07-09)
A general method for the synthesis of 2,4,5-trisubstituted thiazoles has been developed. Starting from commercially available 2-bromothiazole, successive metalations using TMPMgCl·LiCl or TMP(2)Zn·2MgCl(2)·2LiCl lead to the corresponding magnesated or zincated thiazoles which readily react with various electrophiles providing highly functionalized
Synthesis of camalexin and related phytoalexins.
Ayer WA, et al.
Tetrahedron, 48(14), 2919-2924 (1992)
Mohammed Al-Hashimi et al.
Organic letters, 12(23), 5478-5481 (2010-11-12)
The synthesis of a novel electron-deficient fused pyrrolo[3,2-d:4,5-d']bisthiazole is reported from 2-bromothiazole. This was copolymerized with thiophene, selenophene, thienothiophene, and bithiophene by microwave-assisted Stille polycondensation. The resulting polymers exhibited small optical band gaps combined with low-lying HOMO energy levels and
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