Name: 3-甲氧基-2-硝基苯甲醛
Brand: ALDRICH

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About This Item

线性分子式:

CH₃OC₆H₃(NO₂)CHO

CAS Number:

53055-05-3

分子量:

181.15

Beilstein:

1959385

EC 号:

258-332-9

MDL编号:

MFCD00007135

UNSPSC代码:

12352100

PubChem化学物质编号:

24850038

NACRES:

NA.22

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质量水平

100

方案

≥97%

表单

solid

mp

97-101 °C (lit.)

官能团

aldehyde
nitro

SMILES字符串

[H]C(=O)c1cccc(OC)c1[N+]([O-])=O

InChI

1S/C8H7NO4/c1-13-7-4-2-3-6(5-10)8(7)9(11)12/h2-5H,1H3

InChI key

GDTUACILWWLIJF-UHFFFAOYSA-N

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一般描述

3-Methoxy-2-nitrobenzaldehyde undergoes 1,4-diazabicyclo[2.2.2]octane-catalyzed reaction with methyl vinyl ketone (MVK) to afford normal Baylis-Hillman adduct, the MVK dimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts.

应用

3-Methoxy-2-nitrobenzaldehyde was used in the synthesis of 8-hydroxyquinazoline, methy-3-methoxyanthranilate and 3-methoxy-2-nitrobenzylidenebisformamide.