163821
3-甲氧基-2-硝基苯甲醛
≥97%
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关于此项目
线性分子式:
CH3OC6H3(NO2)CHO
化学文摘社编号:
分子量:
181.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
258-332-9
Beilstein/REAXYS Number:
1959385
MDL number:
Assay:
≥97%
Form:
solid
产品名称
3-甲氧基-2-硝基苯甲醛, ≥97%
InChI key
GDTUACILWWLIJF-UHFFFAOYSA-N
InChI
1S/C8H7NO4/c1-13-7-4-2-3-6(5-10)8(7)9(11)12/h2-5H,1H3
SMILES string
[H]C(=O)c1cccc(OC)c1[N+]([O-])=O
assay
≥97%
form
solid
mp
97-101 °C (lit.)
functional group
aldehyde
nitro
Quality Level
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Application
3-Methoxy-2-nitrobenzaldehyde was used in the synthesis of 8-hydroxyquinazoline, methy-3-methoxyanthranilate and 3-methoxy-2-nitrobenzylidenebisformamide.
General description
3-Methoxy-2-nitrobenzaldehyde undergoes 1,4-diazabicyclo[2.2.2]octane-catalyzed reaction with methyl vinyl ketone (MVK) to afford normal Baylis-Hillman adduct, the MVK dimer and a pair of diastereomeric bis-(MVK)Baylis-Hillman adducts.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Elucidation of the complex Baylis-Hillman reaction of 3-methoxy-2-nitrobenzaldehyde with methyl vinyl ketone.
Idahosa KC, et al.
South African Journal of Chemistry, 64, 144-150 (2011)
972. Analogues of 8-hydroxyquinoline having additional cyclic nitrogen atoms. Part I. Preparative.
Albert A and Hampton A.
Journal of the Chemical Society, 4985-4993 (1952)
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