163945
4-氨基-TEMPO,自由基
97%
别名:
4-氨基-2,2,6,6-四甲基哌啶-1-氧, 4-氨基-2,2,6,6-四甲基哌啶氧自由基, 4-氨基-TEMPO
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关于此项目
经验公式(希尔记法):
C9H19N2O
化学文摘社编号:
分子量:
171.26
Beilstein:
3933966
EC 号:
MDL编号:
UNSPSC代码:
12352000
PubChem化学物质编号:
NACRES:
NA.22
应用
可用于研究生物系统、聚合物的自旋标记物,并且可作为更复杂的自旋标记物的结构单元。
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
SEC-MALS analysis of cellouronic acid prepared from regenerated cellulose by TEMPO-mediated oxidation.
Shibata I, et al.
Cellulose, 13(1), 73-80 (2006)
N Naber et al.
Biochemistry, 33(13), 3855-3861 (1994-04-05)
Each actin molecule contains a nucleotide, tightly bound in a deep cleft that divides the molecule. To probe conformational changes within this region of the molecule, we have incorporated two spin label analogues of ATP into actin. In both analogs
Journal of Colloid and Interface Science, 165, 236-236 (1994)
Spin-Labeled Dendrimers in EPR Imaging with Low Molecular Weight Nitroxides.
Alexander T. Yordanov et al.
Angewandte Chemie (International ed. in English), 40(14), 2690-2692 (2001-07-18)
C Mathieu et al.
Free radical research, 27(2), 165-171 (1997-08-01)
The synproportionation reaction between ferryl leghemoglobin and oxyleghemoglobin does not occur, at least under conditions where this process could be clearly demonstrated with myoglobin and hemoglobin. In contrast, a cross synproportionation can occur between oxyleghemoglobin and ferryl myoglobin or between
商品
TEMPO(2,2,6,6-四甲基哌啶氧基或2,2,6,6-四甲基哌啶1-氧基)及其衍生物在有机氧化反应催化剂中可以作为稳定的硝酰基使用。TEMPO由Lebedev和Kazarnovskii于1960年发现,其具有的稳定自由基性质得益于其庞大的取代基团阻碍了自由基与其他分子之间发生反应。
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