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167479

氯丙酮

Name: 氯丙酮
Brand: ALDRICH

95%

别名:

1-氯-2-丙酮, 氯-2-丙酮

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关于此项目

线性分子式:

ClCH₂COCH₃

化学文摘社编号:

78-95-5

分子量:

92.52

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24850211

EC Number:

201-161-1

Beilstein/REAXYS Number:

605369

MDL number:

MFCD00000936

Assay:

95%

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属性

assay

95%

contains

~0.1% Drapex 39 as stabilizer

impurities

~5% 1,1-dichloroacetone and/or mesityl oxide

refractive index

n20/D 1.432 (lit.)

bp

120 °C (lit.)

mp

−44.5 °C

solubility

alcohol: miscible, chloroform: miscible, diethyl ether: miscible

density

1.162 g/mL at 25 °C (lit.)

functional group

chloro, ketone

storage temp.

2-8°C

SMILES string

CC(=O)CCl

InChI

1S/C3H5ClO/c1-3(5)2-4/h2H2,1H3

InChI key

BULLHNJGPPOUOX-UHFFFAOYSA-N

说明

General description

Direct aldol reaction of chloroacetone with of 4-nitrobenzaldehyde catalyzed by L-proline amides has been investigated.

Application

Chloroacetone was used in the synthesis of double-chain nonionic surfactants with an acid decomposition function via acid-catalyzed condensation with fatty alcohols (octyl, decyl and dodecyl). It was also used in the synthesis of meso-tetramethyl tetrakis-(4-phenoxy acetone)calix[4]pyrrole.

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pcodes

P210 - P280 - P301 + P310 + P330 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

pictograms

GHS02,GHS06,GHS05,GHS09

signalword

Danger

hcodes

H226,H301,H310 + H330,H314,H335,H410

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

3 - Flammable liquids

flash_point_f

95.0 °F - closed cup

flash_point_c

35 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Calixpyrrole chemistry: a study of a new ditopic receptor highlighting some fundamental concepts in assessing thermodynamic selectivity.

Angela F Danil de Namor et al.

Physical chemistry chemical physics : PCCP, 12(3), 753-760 (2010-01-13)

Following the synthesis and characterization of meso-tetramethyl tetrakis (4-phenoxy acetone) calix[4]pyrrole, 1, the solution properties of this receptor in various solvents were investigated. Particular emphasis is placed on the selection of the solvent in assessing thermodynamic selectivity in ion complexation

L-Proline amide-catalyzed direct asymmetric aldol reaction of aldehydes with chloroacetone.

He L, et al.

Tetrahedron, 62(2), 346-351 (2006)

Chloroacetone as an active-site-directed inhibitor of the aliphatic amidase from Pseudomonas aeruginosa.

M R Hollaway et al.

The Biochemical journal, 191(3), 811-826 (1980-12-01)

1. Chloroacetone (I) was shown to be an active-site-directed inhibitor of the aliphatic amidase (EC 3.5.1.4) from Pseudomonas aeruginosa strain PAC142.2. This inhibitor reacted with the enzyme in two stages: the first involving the reversible formation of an enzymically inactive

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全球贸易项目编号

货号	GTIN
167479-500G	04061836682736
167479-100G	04061838749598
167479-5G	04061838749604