168769
茚
98%
别名:
Indonaphthene
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关于此项目
经验公式（希尔记法）:
C9H8
化学文摘社编号:
分子量:
116.16
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39011614
UNSPSC Code:
12352100
EC Number:
202-393-6
MDL number:
Beilstein/REAXYS Number:
635873
Assay:
98%
Form:
liquid
InChI key
YBYIRNPNPLQARY-UHFFFAOYSA-N
InChI
1S/C9H8/c1-2-5-9-7-3-6-8(9)4-1/h1-6H,7H2
SMILES string
C1C=Cc2ccccc12
assay
98%
form
liquid
refractive index
n20/D 1.595 (lit.)
bp
181-182 °C (lit.)
mp
−5-−3 °C (lit.)
solubility
organic solvents: miscible, water: insoluble
density
0.996 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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General description
通过 恶臭假单胞菌 和 红球菌 将茚氧化为 顺式 -和 反式 -茚满二醇及相关代谢产物的混合物。
Application
茚用于合成新的 C 60 衍生物茚-C 60 双加合物 。在 CH 2 Cl 2 中，用甲基异丙醚/TiCl 4 引发控制阳离子聚合制备聚茚。
signalword
Danger
hcodes
Hazard Classifications
Asp. Tox. 1 - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
136.4 °F - closed cup
flash_point_c
58 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
High glass transition temperature polyolefins obtained by the catalytic hydrogenation of polyindene.
Hahn SF and Hillmyer MA.
Macromolecules, 36(1), 71-76 (2003)
B C Buckland et al.
Metabolic engineering, 1(1), 63-74 (2000-08-10)
Indene is oxidized to mixtures of cis- and trans-indandiols and related metabolites by Pseudomonas putida and Rhodococcus sp. isolates. Indene metabolism is consistent with monooxygenase and dioxygenase activity. P. putida resolves enantiomeric mixtures of cis-1,2-indandiol by further selective oxidation of
Lucas J Gursky et al.
Applied microbiology and biotechnology, 85(4), 995-1004 (2009-07-02)
The styAB genes from Pseudomonas putida CA-3, which encode styrene monooxygenase, were subjected to three rounds of in vitro evolution using error-prone polymerase chain reaction with a view to improving the rate of styrene oxide and indene oxide formation. Improvements
Regioselective synthesis of indenols by rhodium-catalyzed C-H activation and carbocyclization of aryl ketones and alkynes.
Krishnamoorthy Muralirajan et al.
Angewandte Chemie (International ed. in English), 50(18), 4169-4172 (2011-03-31)
Adam C Glass et al.
Organic letters, 10(21), 4855-4857 (2008-10-07)
A new methodology for the preparation of substituted naphthalenes starting from readily available indenones, organometal reagents, and trimethylsilyldiazomethane via a catalytic rearrangement process is described. Hindered biaryl naphthalenes, including triortho-substituted biaryls, can be accessed through our method. Our results are
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