169897
1-苯基-1H-四唑-5-硫醇
98%
别名:
1-苯基-5-巯基四氮唑, 1-苯基四氮唑-5-硫醇, 5-巯基-1-苯基四氮唑
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关于此项目
经验公式（希尔记法）:
C7H6N4S
化学文摘社编号:
分子量:
178.21
EC Number:
201-710-5
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
139068
MDL number:
Assay:
98%
Form:
powder
InChI key
GGZHVNZHFYCSEV-UHFFFAOYSA-N
InChI
1S/C7H6N4S/c12-7-8-9-10-11(7)6-4-2-1-3-5-6/h1-5H,(H,8,10,12)
SMILES string
Sc1nnnn1-c2ccccc2
assay
98%
form
powder
mp
145 °C (dec.) (lit.)
solubility
ethanol: soluble 5%, clear, colorless to faintly yellow
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Application
1-Phenyl-1H-tetrazole-5-thiol was used in the synthesis of oxacyclic building blocks via highly stereoselective radical cyclization and olefin metathesis reactions. It was also used in the synthesis of metalated tetradecyl sulfone.
General description
1-Phenyl-1H-tetrazole-5-thiol is an effective inhibitor of aluminum corrosion in 1M HCl solution.
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 4 - Eye Irrit. 2 - Flam. Sol. 1 - Skin Sens. 1
存储类别
4.1A - Other explosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
监管及禁止进口产品
此项目有
A formal synthesis of 3-O-(4-methoxybenzyl)-azidosphingosine by a modified Julia olefination.
Compostella F, et al.
Tetrahedron, 58(22), 4425-4428 (2002)
The inhibitive effect of some tetrazole derivatives towards Al corrosion in acid solution: Chemical, electrochemical and theoretical studies.
Khaled KF and Al-Qahtani MM.
Materials Chemistry and Physics, 113(1), 150-158 (2009)
Mohammad M Khodaei et al.
The Journal of organic chemistry, 73(7), 2527-2532 (2008-03-05)
In the presence of 1-phenyl-5-mercaptotetrazole as a nucleophile, electrochemical oxidations of 1,2- and 1,4-dihydroxybenzenes have been investigated in aqueous solution using cyclic voltammetry and controlled-potential coulometry. The voltammetric results indicate that an electrooxidative/Michael-type sequential reaction occurs between the mercaptide anion
Total synthesis of ambruticin.
Eun Lee et al.
Angewandte Chemie (International ed. in English), 41(1), 176-178 (2002-12-20)
K Nesmĕrák et al.
Folia microbiologica, 45(2), 138-142 (2001-03-29)
The antifungal effect of substituted 1-phenyl-5-mercaptotetrazoles was tested with Candida tropicalis, C. pseudotropicalis, C. mogii, Trichosporon cutaneum, Cryptococcus albidus and S. cerevisiae. Candida strains exhibited the lowest sensitivity to the compounds; the most sensitive was S. cerevisiae. The MIC values
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