175064
亚硝四氟硼酸盐
95%
别名:
四氟硼酸亚硝
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关于此项目
线性分子式:
NOBF4
化学文摘社编号:
分子量:
116.81
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
238-679-2
MDL number:
Assay:
95%
Quality Level
assay
95%
reaction suitability
reagent type: oxidant
storage temp.
2-8°C
SMILES string
N#[O+].F[B-](F)(F)F
InChI
1S/BF4.NO/c2-1(3,4)5;1-2/q-1;+1
InChI key
KGCNVGDHOSFKFT-UHFFFAOYSA-N
Application
四氟硼酸亚硝盐是一种有效的亚硝化和重氮化剂。它与醇和仲胺反应，分别产生亚硝酸烷基酯和亚硝胺。它与伯胺反应，生成重氮四氟硼酸盐。NOBF4也是一种温和的氧化剂，常用于单电子转移氧化反应。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
S Mohr et al.
FEBS letters, 348(3), 223-227 (1994-07-18)
Previous studies have suggested that glyceraldehyde-3-phosphate dehydrogenase (GAPDH) undergoes covalent modification of an active site thiol by a NO.-induced [32P]NAD(+)-dependent mechanism. However, the efficacy of GAPDH modification induced by various NO donors was found to be independent of spontaneous rates
S Mohr et al.
The Journal of biological chemistry, 274(14), 9427-9430 (1999-03-27)
S-Nitrosylation of protein thiol groups by nitric oxide (NO) is a widely recognized protein modification. In this study we show that nitrosonium tetrafluoroborate (BF4NO), a NO+ donor, modified the thiol groups of glyceraldehyde-3-phosphate dehydrogenase (GAPDH) by S-nitrosylation and caused enzyme
Electronically regulated thermally and light-gated electron transfer from anions to naphthalenediimides.
Guha, Samit et al.
Journal of the American Chemical Society, 133(39), 15256-15259 (2011)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 175064-5G | 04061838752178 |
| 175064-50G | 04061833554395 |
| 175064-25G | 04061838752161 |