175064
亚硝四氟硼酸盐
95%
别名:
四氟硼酸亚硝
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关于此项目
线性分子式:
NOBF4
化学文摘社编号:
分子量:
116.81
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
238-679-2
MDL number:
Assay:
95%
InChI key
KGCNVGDHOSFKFT-UHFFFAOYSA-N
InChI
1S/BF4.NO/c2-1(3,4)5;1-2/q-1;+1
SMILES string
N#[O+].F[B-](F)(F)F
assay
95%
reaction suitability
reagent type: oxidant
storage temp.
2-8°C
Quality Level
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Application
四氟硼酸亚硝盐是一种有效的亚硝化和重氮化剂。它与醇和仲胺反应，分别产生亚硝酸烷基酯和亚硝胺。它与伯胺反应，生成重氮四氟硼酸盐。NOBF4也是一种温和的氧化剂，常用于单电子转移氧化反应。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Electronically regulated thermally and light-gated electron transfer from anions to naphthalenediimides.
Guha, Samit et al.
Journal of the American Chemical Society, 133(39), 15256-15259 (2011)
S Mohr et al.
FEBS letters, 348(3), 223-227 (1994-07-18)
Previous studies have suggested that glyceraldehyde-3-phosphate dehydrogenase (GAPDH) undergoes covalent modification of an active site thiol by a NO.-induced [32P]NAD(+)-dependent mechanism. However, the efficacy of GAPDH modification induced by various NO donors was found to be independent of spontaneous rates
J Li et al.
Biochemical and biophysical research communications, 240(2), 419-424 (1997-12-06)
The caspases are a family of at least 10 human cysteine proteases that participate in cytokine maturation and in apoptotic signal transduction and execution mechanisms. Peptidic inhibitors of these enzymes are capable of blocking cytokine maturation and apoptosis, demonstrating their
S Mohr et al.
The Journal of biological chemistry, 274(14), 9427-9430 (1999-03-27)
S-Nitrosylation of protein thiol groups by nitric oxide (NO) is a widely recognized protein modification. In this study we show that nitrosonium tetrafluoroborate (BF4NO), a NO+ donor, modified the thiol groups of glyceraldehyde-3-phosphate dehydrogenase (GAPDH) by S-nitrosylation and caused enzyme
C Würth et al.
Nanoscale, 9(12), 4283-4294 (2017-03-16)
The rational design of brighter upconversion nanoparticles (UCNPs) requires a better understanding of the radiationless deactivation pathways in these materials. Here, we demonstrate the potential of excitation power density (P)-dependent studies of upconversion (UC) luminescence intensities, slope factors, and absolute
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