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179760

2-乙酰基环己酮

Name: 2-乙酰基环己酮
Brand: ALDRICH

97%

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关于此项目

线性分子式:

CH₃COC₆H₉(=O)

化学文摘社编号:

874-23-7

分子量:

140.18

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24850652

EC Number:

212-858-5

Beilstein/REAXYS Number:

1858621

MDL number:

MFCD00001633

Assay:

97%

Form:

liquid

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属性

Quality Level

200

assay

97%

form

liquid

refractive index

n20/D 1.509 (lit.)

bp

111-112 °C/18 mmHg (lit.)

density

1.078 g/mL at 25 °C (lit.)

functional group

ketone

SMILES string

CC(=O)C1CCCCC1=O

InChI

1S/C8H12O2/c1-6(9)7-4-2-3-5-8(7)10/h7H,2-5H2,1H3

InChI key

OEKATORRSPXJHE-UHFFFAOYSA-N

说明

General description

已经研究了2-乙酰基环己酮（ACHE）在水中的酮-烯醇互变异构现象。

Application

2-乙酰环己酮被用于合成苯氨基乙醇胺。

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

174.2 °F - closed cup

flash_point_c

79 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

历史批次信息供参考:

分析证书(COA)

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Nitrosation of 2-acetylcyclohexanone. 2. Reaction in water in the absence and presence of cyclodextrins.

Emilia Iglesias

The Journal of organic chemistry, 68(7), 2689-2697 (2003-03-29)

The kinetic study of the nitrosation of the enol of 2-acetylcyclohexanone (ACHE) has been performed in aqueous acid media in the absence and presence of alpha- and beta-cyclodextrin. The reaction is first-order with respect to both reactants concentration: [nitrite] and

Tautomerization of 2-acetylcyclohexanone. 1. Characterization of keto-enol/enolate equilibria and reaction rates in water.

Emilia Iglesias

The Journal of organic chemistry, 68(7), 2680-2688 (2003-03-29)

The keto-enol tautomerism of 2-acetylcyclohexanone (ACHE) was studied in water under different experimental conditions. By contrast with other previously studied beta-diketones, the keto-enol interconversion in the ACHE system is a slow process. Under equilibrium conditions, the analysis of the absorbance

Copper-catalyzed amination of (bromophenyl)ethanolamine for a concise synthesis of aniline-containing analogues of NMDA NR2B antagonist ifenprodil.

Cédric Bouteiller et al.

Organic & biomolecular chemistry, 8(5), 1111-1120 (2010-02-19)

An operationally simple and concise synthesis of anilinoethanolamines, as NMDA NR2B receptor antagonist ifenprodil analogues, was developed via a copper-catalyzed amination of the corresponding bromoarene. Coupling was achieved with linear primary alkylamines, alpha,omega-diamines, hexanolamine and benzophenone imine, as well as

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全球贸易项目编号

货号	GTIN
179760-25G	04061838346636
179760-5G	04061838754448