183717
邻氟苯乙酮
97%
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关于此项目
线性分子式:
FC6H4COCH3
化学文摘社编号:
分子量:
138.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-156-0
Beilstein/REAXYS Number:
2041344
MDL number:
Assay:
97%
Form:
liquid
InChI key
QMATYTFXDIWACW-UHFFFAOYSA-N
InChI
1S/C8H7FO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
SMILES string
CC(=O)c1ccccc1F
assay
97%
form
liquid
refractive index
n20/D 1.507 (lit.)
bp
187-189 °C (lit.)
density
1.137 g/mL at 20 °C (lit.)
General description
The enantioselective reduction of 2′-fluoroacetophenone has been investigated.
Application
2′-Fluoroacetophenone was used as starting reagent in the synthesis of ascididemin.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
The enantioselective reduction of 2'-fluoroacetophenone utilizing a simplified CBS-reduction procedure.
Garrett CE, et al.
Tetrahedron Asymmetry, 13(13), 1347-1349 (2002)
Ida Nymann Petersen et al.
Chemical communications (Cambridge, England), 48(72), 9092-9094 (2012-08-07)
A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2'-fluoroacetophenone. This new approach was extended
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