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183717

邻氟苯乙酮

Name: 邻氟苯乙酮
Brand: ALDRICH

97%

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关于此项目

线性分子式:

FC₆H₄COCH₃

化学文摘社编号:

445-27-2

分子量:

138.14

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24851072

EC Number:

207-156-0

Beilstein/REAXYS Number:

2041344

MDL number:

MFCD00000320

Assay:

97%

Form:

liquid

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属性

assay

97%

form

liquid

refractive index

n20/D 1.507 (lit.)

bp

187-189 °C (lit.)

density

1.137 g/mL at 20 °C (lit.)

SMILES string

CC(=O)c1ccccc1F

InChI

1S/C8H7FO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3

InChI key

QMATYTFXDIWACW-UHFFFAOYSA-N

说明

General description

The enantioselective reduction of 2′-fluoroacetophenone has been investigated.

Application

2′-Fluoroacetophenone was used as starting reagent in the synthesis of ascididemin.

pictograms

GHS07

signalword

Warning

hcodes

H315,H319

pcodes

P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

143.6 °F - closed cup

flash_point_c

62 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Total synthesis of ascididemin via anionic cascade ring closure.

Ida Nymann Petersen et al.

Chemical communications (Cambridge, England), 48(72), 9092-9094 (2012-08-07)

A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2'-fluoroacetophenone. This new approach was extended

The enantioselective reduction of 2'-fluoroacetophenone utilizing a simplified CBS-reduction procedure.

Garrett CE, et al.

Tetrahedron Asymmetry, 13(13), 1347-1349 (2002)

全球贸易项目编号

货号	GTIN
183717-5G	04061838756367