184357
(苯磺酰)乙腈
98%
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关于此项目
线性分子式:
C6H5SO2CH2CN
化学文摘社编号:
分子量:
181.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
231-515-0
Beilstein/REAXYS Number:
640716
MDL number:
Assay:
98%
Form:
solid
InChI key
ZFCFFNGBCVAUDE-UHFFFAOYSA-N
InChI
1S/C8H7NO2S/c9-6-7-12(10,11)8-4-2-1-3-5-8/h1-5H,7H2
SMILES string
O=S(=O)(CC#N)c1ccccc1
assay
98%
form
solid
mp
112-114 °C (lit.)
functional group
nitrile, sulfone
Quality Level
General description
Condensation reaction of (phenylsulfonyl)acetonitrile with benzaldehyde in water in heterogeneous phase in the presence and absence of anionic and cationic surfactants has been studied. Dehydrative alkylation of alcohols with (phenylsulfonyl)acetonitrile under modified Mitsunobu conditions has been investigated.
Application
(Phenylsulfonyl)acetonitrile was used in the synthesis of pyridines, chromenes and thiophene derivatives based on sulfones.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Condensation reactions in water of active methylene compounds with arylaldehydes. One-pot synthesis of flavonols.
Fringuelli F, et al.
Tetrahedron, 50(39), 11499-11508 (1994)
Two-carbon elongation/annulation of alcohols to nitriles.
Lai J-Y, et al.
Tetrahedron Letters, 36(32), 5691-5694 (1995)
Utility of sulphones in heterocyclic synthesis: Synthesis of some pyridine, chromene and thiophene derivatives.
Fadda AA, et al.
Macromolecules, 5(5), 701-709 (2000)
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