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184837

)-2-氨基-3-甲基-1-丁醇

Name: )-2-氨基-3-甲基-1-丁醇
Brand: ALDRICH

97%

别名:

DL-缬氨醇

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关于此项目

线性分子式:

(CH₃)₂CHCH(NH₂)CH₂OH

化学文摘社编号:

16369-05-4

分子量:

103.16

UNSPSC Code:

12352100

PubChem Substance ID:

24850658

EC Number:

240-425-0

MDL number:

MFCD00004730

Assay:

97%

Form:

liquid

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属性

assay

97%

form

liquid

refractive index

n20/D 1.4543 (lit.)

bp

75-77 °C/8 mmHg (lit.)

density

0.936 g/mL at 25 °C (lit.)

functional group

amine, hydroxyl

SMILES string

CC(C)C(N)CO

InChI

1S/C5H13NO/c1-4(2)5(6)3-7/h4-5,7H,3,6H2,1-2H3

InChI key

NWYYWIJOWOLJNR-UHFFFAOYSA-N

说明

Application

2-氨基-3-甲基-1-丁醇被用于合成1-烯丙基-2-吡咯烷酮。它也被用作手性亲核试剂，用于合成贝娜诺霉素-普纳米星类抗生素。在合成包含两个手性亚基的冠醚时，它被用作同手性客体化合物。

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

194.0 °F - closed cup

flash_point_c

90 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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A long-range chiral relay via tertiary amide group in asymmetric catalysis: new amino acid-derived N,P-ligands for copper-catalysed conjugate addition.

Andrei V Malkov et al.

Chemical communications (Cambridge, England), (15)(15), 1948-1949 (2003-08-23)

New N,P-ligands 4-6, derived from valinol and prolinol, respectively, have been developed for the asymmetric, copper(I)-catalysed conjugate addition of diethylzinc to unsaturated ketones; the tertiary amide group has been shown to effectively relay the chiral information from the ligand backbone

Preparation of homochiral phenolic crown ethers containing para-substituted phenol moiety and chiral subunits derived from (S)-1-phenylethane-1, 2-diol: their chiral recognition behaviour in complexation with neutral amines.

Naemura K, et al.

Tetrahedron Asymmetry, 8(6), 873-882 (1997)

Asymmetric synthesis of 8-aminoindolizidine from chiral 2-pyrroleimines.

Vincenzo Giulio Albano et al.

The Journal of organic chemistry, 73(21), 8376-8381 (2008-10-02)

1-Allyl-2-pyrroleimines obtained from (S)-valinol and (S)-phenylglycinol underwent highly diastereoselective addition of allylmagnesium chloride, used in excess amounts, to give the corresponding secondary amines with concomitant allyl to (Z)-1-propenyl isomerization of the 1-pyrrole substituent. Transformation of the 2-amino alcohol moiety to

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全球贸易项目编号

货号	GTIN
184837-5G	04061838756794
184837-1G	04061837006142