184837
)-2-氨基-3-甲基-1-丁醇
97%
别名:
DL-缬氨醇
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关于此项目
线性分子式:
(CH3)2CHCH(NH2)CH2OH
化学文摘社编号:
分子量:
103.16
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
240-425-0
MDL number:
产品名称
)-2-氨基-3-甲基-1-丁醇, 97%
InChI key
NWYYWIJOWOLJNR-UHFFFAOYSA-N
InChI
1S/C5H13NO/c1-4(2)5(6)3-7/h4-5,7H,3,6H2,1-2H3
SMILES string
CC(C)C(N)CO
assay
97%
form
liquid
refractive index
n20/D 1.4543 (lit.)
bp
75-77 °C/8 mmHg (lit.)
density
0.936 g/mL at 25 °C (lit.)
functional group
amine
hydroxyl
Application
2-氨基-3-甲基-1-丁醇被用于合成1-烯丙基-2-吡咯烷酮。 它也被用作手性亲核试剂，用于合成贝娜诺霉素-普纳米星类抗生素。在合成包含两个手性亚基的冠醚时，它被用作同手性客体化合物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
194.0 °F - closed cup
flash_point_c
90 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Andrei V Malkov et al.
Chemical communications (Cambridge, England), (15)(15), 1948-1949 (2003-08-23)
New N,P-ligands 4-6, derived from valinol and prolinol, respectively, have been developed for the asymmetric, copper(I)-catalysed conjugate addition of diethylzinc to unsaturated ketones; the tertiary amide group has been shown to effectively relay the chiral information from the ligand backbone
Vincenzo Giulio Albano et al.
The Journal of organic chemistry, 73(21), 8376-8381 (2008-10-02)
1-Allyl-2-pyrroleimines obtained from (S)-valinol and (S)-phenylglycinol underwent highly diastereoselective addition of allylmagnesium chloride, used in excess amounts, to give the corresponding secondary amines with concomitant allyl to (Z)-1-propenyl isomerization of the 1-pyrrole substituent. Transformation of the 2-amino alcohol moiety to
Preparation of homochiral phenolic crown ethers containing para-substituted phenol moiety and chiral subunits derived from (S)-1-phenylethane-1, 2-diol: their chiral recognition behaviour in complexation with neutral amines.
Naemura K, et al.
Tetrahedron Asymmetry, 8(6), 873-882 (1997)
Minoru Tamiya et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(35), 9791-9823 (2007-10-02)
A general approach to the regio- and stereoselective total synthesis of the benanomicin-pradimicin antibiotics (BpAs) is described. Construction of the aglycon has been achieved by 1) the diastereoselective ring-opening of a biaryl lactone by using (R)-valinol as a chiral nucleophile
Peter Møller et al.
Mutation research, 527(1-2), 91-97 (2003-06-06)
Earlier studies have indicated that sucrose increases 2-amino-3-methylimidazo[4,5-f]quinoline (IQ)-induced aberrant crypt foci in the colon. In this study, we investigated the role of sucrose in IQ-induced genotoxicity of the colon mucosa and liver. Big Blue rats were fed with IQ
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