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Merck
CN

185981

4-硝基二苯硫醚

97%

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关于此项目

线性分子式:
O2NC6H4SC6H5
化学文摘社编号:
952-97-6
分子量:
231.27
UNSPSC Code:
12352100
PubChem Substance ID:
24851194
EC Number:
213-462-5
MDL number:
MFCD00024700
Assay:
97%
Form:
solid

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assay

97%

form

solid

mp

52-55 °C (lit.)

SMILES string

[O-][N+](=O)c1ccc(Sc2ccccc2)cc1

InChI

1S/C12H9NO2S/c14-13(15)10-6-8-12(9-7-10)16-11-4-2-1-3-5-11/h1-9H

InChI key

RJCBYBQJVXVVKB-UHFFFAOYSA-N

General description

4-Nitrophenyl phenyl sulfide participates in copper-catalysed S-arylation of thiophenol derivatives with aryl halides.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
09112CH
U21035
04029TE
08516LA

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Mónica Carril et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(18), 5100-5105 (2007-03-28)
A novel protocol for the copper-catalysed S-arylation of thiophenol derivatives with aryl halides leading to diaryl sulfides is reported. The reactions were catalysed by a combination of a copper salt and a 1,2-diamine derivative (acting both as the ligand and
T R Juneja et al.
Mutation research, 263(1), 13-19 (1991-05-01)
4-Nitrodiphenyl thioether (4-NO2TE) and its various potential metabolites 4-nitroso- (4-NOTE), 4-hydroxylamino- (4-NHOHTE), 4-hydroxyacetylamino- [4-N(OH)ACTE], 4-acetoxy-acetylamino- [4-N(OAc)-ACTE], 4-amino- (4-ATE) and 4-acetamido- (4-AATE) were tested for their mutagenicity toward Salmonella typhimurium TA98 in the presence and absence of S9 activation system. 4-NO2TE

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