187518
2,6-二氯苯甲酰氯
99%
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关于此项目
线性分子式:
Cl2C6H3COCl
化学文摘社编号:
分子量:
209.46
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39050513
UNSPSC Code:
12352100
EC Number:
225-102-4
MDL number:
Beilstein/REAXYS Number:
639531
产品名称
2,6-二氯苯甲酰氯, 99%
InChI key
JBLIDPPHFGWTKU-UHFFFAOYSA-N
InChI
1S/C7H3Cl3O/c8-4-2-1-3-5(9)6(4)7(10)11/h1-3H
SMILES string
ClC(=O)c1c(Cl)cccc1Cl
assay
99%
form
liquid
refractive index
n20/D 1.560 (lit.)
bp
142-143 °C/21 mmHg (lit.)
mp
15-17 °C
density
1.462 g/mL at 25 °C (lit.)
functional group
acyl chloride
chloro
Quality Level
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Application
2,6-Dichlorobenzoyl chloride was used:
- in substrate activity screening method for the rapid development of novel substrates and their conversion into non-peptidic inhibitors of Cys and Ser proteases
- in the synthesis of 1-acyliridoles
- in enantiocontrolled total synthesis of (-)-aspicilin
General description
2,6-Dichlorobenzoyl chloride participates in esterification of (fluoren-9-ylmethoxy)carbonyl (Fmoc)-amino acids to 4-alkoxybenzyl alcohol polystyrene.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Morphine recognition by a porphyrin-cyclocholate molecular bowl.
Bonar-Law RP, et al.
Journal of the Chemical Society. Chemical Communications, 5, 456-458 (1993)
An improved method for anchoring of 9-fluorenylmethoxycarbonyl-amino acids to 4-alkoxybenzyl alcohol resins.
Sieber, P.
Tetrahedron Letters, 28(49), 6147-6150 (1987)
Sensitisation to dichlorobenzoyl chloride.
J De Boer et al.
Contact dermatitis, 18(2), 116-117 (1988-02-01)
Andrew W Patterson et al.
Nature protocols, 2(2), 424-433 (2007-04-05)
Substrate activity screening (SAS) is a fragment-based method for the rapid development of novel substrates and their conversion into non-peptidic inhibitors of Cys and Ser proteases. The method consists of three steps: (i) a library of N-acyl aminocoumarins with diverse
Stereocontrolled total synthesis of the macrocyclic lactone (-)-aspicilin.
Waanders PP, et al.
Tetrahedron Letters, 28(21), 2409-2412 (1987)
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