194654
菊醇，顺反异构体混合物
98%
别名:
2,2-二甲基-3-(2-甲基丙烯基)环丙甲醇, 野菊花醇
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线性分子式:
(CH3)2C3H2[CH=C(CH3)2]CH2OH
化学文摘社编号:
分子量:
154.25
UNSPSC Code:
12352100
PubChem Substance ID:
EC Number:
227-045-0
MDL number:
InChI key
HIPIENNKVJCMAP-UHFFFAOYSA-N
InChI
1S/C10H18O/c1-7(2)5-8-9(6-11)10(8,3)4/h5,8-9,11H,6H2,1-4H3
SMILES string
C\C(C)=C\C1C(CO)C1(C)C
assay
98%
refractive index
n20/D 1.475 (lit.)
bp
66-69 °C/0.07 mmHg (lit.)
density
0.888 g/mL at 25 °C (lit.)
General description
Oxidation of chrysanthemyl alcohol in the presence of [RuO4]2- yields chrysantheniic acid.
Application
Chrysanthemyl alcohol was used in the determination of position of double bonds in various terepenes and branched chain compounds.
Oxo complexes of ruthenium (VI) and (VII) as organic oxidants.
Green G, et al.
Journal of the Chemical Society. Perkin Transactions 1, 681-686 (1984)
A B Attygalle et al.
Analytical chemistry, 65(18), 2528-2533 (1993-09-15)
The electron-impact mass spectra of alpha, beta-bis(methylthio) derivatives of certain terpenes and other compounds with branched alkenyl groups contain diagnostic peaks that can be used for locating the position of the double bond in the parent compound. In contrast to
[Studies on the chemical constituents of Chrysanthemum indicum L].
D Q Yu et al.
Yao xue xue bao = Acta pharmaceutica Sinica, 22(11), 837-840 (1987-11-01)
L Y Mou et al.
Journal of Asian natural products research, 3(2), 103-116 (2001-06-16)
Chrysanthemol (1), a trans-eudesmane type sesquiterpene from Chrysanthemum indicum L., possesses certain anti-inflammatory activity. Its total synthesis was approached from two alternative routes and finally accomplished in ten steps from R-(+)-carvone via alpha-eudesmol (10) as the key intermediate. The overall
Gas chromatographic determination of racemic cis- and trans-chrysanthemols and their potential aldehyde and carboxylic acid microbial metabolites.
M Miski et al.
Journal of chromatography, 437(2), 436-441 (1988-03-25)
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