表单
liquid
反应适用性
reagent type: reductant
浓度
1.0 M in hexanes
密度
0.675 g/mL at 25 °C
SMILES字符串
CCB(CC)CC
InChI
1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
InChI key
LALRXNPLTWZJIJ-UHFFFAOYSA-N
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应用
三乙基硼烷可用于：
- 在水介质中作为自由基反应的自由基引发剂和终止剂。（1）
- 通过与2-取代的烯丙基胂叶立德反应合成聚（2-取代-1-亚丙烯基）聚合物。（2）
作为催化剂用于：
N -杂环卡宾硼烷还原烷基溴的反应物
具有氧化电位的四甲基铵三烷基苯硼酸酯盐合成用反应物
- 醛的烯丙基化
- 脱羧酶 C-C 键断裂反应
- 氢化铼/硼路易斯酸共催化烯烃加氢反应
- 不饱和肟醚的区域选择性羟基烷基化
N -杂环卡宾硼烷还原烷基溴的反应物
具有氧化电位的四甲基铵三烷基苯硼酸酯盐合成用反应物
警示用语：
Danger
危险分类
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1A - STOT RE 1 Inhalation - STOT SE 3
靶器官
Central nervous system, Nervous system
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
闪点(°F)
-32.8 °F
闪点(°C)
-36 °C
法规信息
危险化学品
此项目有
Free-radical reaction of imine derivatives in water.
Miyabe H, et al.
The Journal of Organic Chemistry, 65(16), 5043-5047 (2000)
Synthesis of poly (2-substituted-1-propenylene)s from allylic arsonium ylides.
Mondiere R, et al.
Macromolecules, 38(3), 663-668 (2005)
H Miyabe
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 120(8), 667-676 (2000-08-18)
Triethylborane has the potential to induce radical reactions on solid support and the solid-phase radical reactions were achieved by using triethylborane as a radical initiator. The intermolecular carbon radical addition to glyoxylic oxime ether anchored to Wang resin proceeded under
Hideto Miyabe et al.
Chemical & pharmaceutical bulletin, 52(7), 842-847 (2004-07-17)
Tandem radical addition-cyclization of oxime ethers anchored to polymer support was studied. The reaction of oxime ethers with stannyl radical proceeded effectively by the use of triethylborane as a radical initiator. The alkyl radical addition-cyclization reactions of oxime ether connected
Masanari Kimura et al.
Organic letters, 11(17), 3794-3797 (2009-08-12)
Rh(I) catalyzes the reductive coupling reaction of a wide variety of aldehydes with conjugated dienes in the presence of a stoichiometric amount of triethylborane to provide homoallyl alcohols in a single operation.
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