196215
双(环戊二烯基)二氯化锆(IV)
≥98%, solid
别名:
二氯二茂, 二氯化双环戊二烯锆, 二氯双环戊二烯锆, 二(环戊二烯基)二氯化锆(IV), 二氯二茂锆
产品名称
双(环戊二烯基)二氯化锆(IV), ≥98%
方案
≥98%
表单
solid
反应适用性
core: zirconium
reaction type: Polymerization Reactions
reagent type: catalyst
reaction type: Olefin Metathesis
环保替代产品特性
Catalysis
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参数
moisture sensitive
mp
242-245 °C (lit.)
环保替代产品分类
, Aligned
储存温度
2-8°C
SMILES字符串
Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.2ClH.Zr/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI key
QRUYYSPCOGSZGQ-UHFFFAOYSA-L
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一般描述
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。详细信息见于此处。
二氯二茂锆可用作催化剂，从而实现吡咯的高效催化，产率高，简化纯化过程。
二氯二茂锆可用作催化剂，从而实现吡咯的高效催化，产率高，简化纯化过程。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Shizue Mito et al.
Chemical communications (Cambridge, England), (19)(19), 2495-2496 (2005-05-12)
Zirconocene-alkyne complexes prepared from Cp2ZrBu2, phosphines and alkynes reacted with CO to give double carbonylation products, 4-hydroxycyclobuten-1-one derivatives after hydrolysis.
Hydroamination/cyclization of aminoalkenes using cationic zirconocene and titanocene catalysts.
Denis V Gribkov et al.
Angewandte Chemie (International ed. in English), 43(41), 5542-5546 (2004-10-16)
Jozef Stec et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(17), 4896-4904 (2011-03-23)
Tandem insertion of 1,1-dihalo-1-lithio species (halocarbenoids) and lithium alkynides into zirconacyclopentenes and zirconcyclopentanes affords carbocyclic products in high yields via an unusual rearrangement that probably involves addition of an organolithium species to the β-position of a zirconium-alkyne complex to give
Shuzhi Dong et al.
Organic letters, 8(11), 2429-2431 (2006-05-19)
[reaction: see text] An asymmetric route from the epimeric beta-hydroxy esters 4 and 5 to the densely functionalized (+)-10 and (-)-10, respectively, is described. Either cyclobutanol can be made available as the predominant product. The levorotatory antipode has been transformed
Peter Wipf et al.
Organic letters, 7(3), 483-485 (2005-01-28)
[reaction: see text] Hydrozirconation of terminal alkynes, followed by AgClO4-catalyzed in situ addition of the resultant alkenylzirconocenes to 1,2-anhydrosugars (glycal epoxides) leads to alpha-C-glycosides in moderate to high yields.
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