196517
9-氯甲基蒽
≥98%
别名:
9-Anthracenylmethyl chloride
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关于此项目
经验公式(希尔记法):
C15H11Cl
化学文摘社编号:
分子量:
226.70
Beilstein:
1873394
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
方案
≥98%
mp
138-140 °C (lit.)
SMILES字符串
ClCc1c2ccccc2cc3ccccc13
InChI
1S/C15H11Cl/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9H,10H2
InChI key
PCVRSXXPGXRVEZ-UHFFFAOYSA-N
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应用
Protecting reagent for carboxylic acids, phenols, thiophenols, and mercaptans.
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
法规信息
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Fijten, M. W., Haensch, C., van Lankvelt, B. M., Hoogenboom, R., & Schubert, U. S.
Macromolecular Chemistry and Physics, 209(18), 1887-1895 (2008)
9 (chloromethyl) anthracene: a useful derivatizing reagent for enhanced ultraviolet and fluorescence detection of carboxylic acids with liquid chromatography
Korte, W. D
Journal of Chromatography A, 243(1), 153-157 (1982)
A significant fluorescence quenching of anthrylaminobenzocrown ethers by paramagnetic metal cations
Chang, J. H., Choi, Y. M., & Shin, Y. K.
Bull. Korean Chem. Soc., 22(5), 527-530 (2001)
Dorothea F K Rawn et al.
Journal of chromatography. A, 1080(2), 148-156 (2005-07-13)
A rapid and simple method for confirmation of the diarrhetic shellfish poisons (DSP): okadaic acid (OA), dinophysistoxin-1 (DTX-1) and dinophysistoxin-2 (DTX-2) using fluorescence detection following derivatization with 9-chloromethylanthracene, has been established as an alternate to LC/MS. Exposure of the anthrylmethyl
J F Lawrence et al.
Journal of chromatography. A, 721(2), 359-364 (1996-01-19)
The reagent 9-chloromethylanthracene was evaluated for derivatization of the diarrhetic shellfish poisons, okadaic acid and dinophysistoxin-1 (DTX-1), to form fluorescent products separable by liquid chromatography. The toxins were reacted with the reagent in acetonitrile in the presence of tetramethylammonium hydroxide
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