19997
叔丁基过氧化氢 溶液
packed in FEP bottles, ~5.5 M in decane (over molecular sieve 4Å)
别名:
1,1-二甲基乙基-过氧化氢, 2-过氧化氢-2-甲基丙烷, TBHP
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关于此项目
线性分子式:
(CH3)3COOH
化学文摘社编号:
分子量:
90.12
Beilstein:
1098280
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23
表单
liquid
质量
packed in FEP bottles
反应适用性
reagent type: oxidant
浓度
52.9-66.8% (iodometric)
~5.5 M in decane (over molecular sieve 4Å)
折射率
n20/D 1.403
密度
0.83 g/mL at 20 °C
储存温度
2-8°C
SMILES字符串
CC(C)(C)OO
InChI
1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
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应用
用于燃料的氧化脱硫以及作为苯乙烯环氧化的氧化剂。
其他说明
用于Sharpless环氧化的安全稳定的氧化剂
警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 3
闪点(°F)
109.4 °F - closed cup
闪点(°C)
43 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Controlled synthesis of a- and c-Fe2O3 nanoparticles via thermolysis of PVA gels and studies on a-Fe2O3 catalyzed styrene epoxidation.
Bepari RA,et al.
Journal of Saudi Chemical Society (2014)
Oxidative desulfurization of fuel oil. Part I. Oxidation of dibenzothiphenes using tert-butyl hydroperoxide
Wang D,et al.
Applied Catalysis A: General, 253, 91-99 (2003)
K. Akashi et al.
The Journal of Organic Chemistry, 43, 2063-2063 (1978)
T. Katsuki et al.
Org. React., 48, 1-1 (1996)
Qiong Tang et al.
Ultrasonics sonochemistry, 20(5), 1168-1175 (2013-03-30)
This work investigated the ultrasonic assisted oxidative desulfurization of bunker-C oil with TBHP/MoO3 system. The operational parameters for the desulfurization procedure such as ultrasonic irradiation time, ultrasonic wave amplitude, catalyst initial concentration and oxidation agent initial concentration were studied. The
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