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20021

3-叔丁基-4-羟基苯甲醚

Name: 3-<I>叔丁基</I>-4-羟基苯甲醚
Brand: ALDRICH

≥98% (sum of isomers, GC), ≤10% 2-BHA basis (GC)

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别名:

2-叔丁基-4-甲氧基苯酚, 3-BHA, BHA

经验公式（希尔记法）:

C₁₁H₁₆O₂

CAS号:

121-00-6

分子量:

180.24

Beilstein:

1867499

EC 号:

204-442-7

MDL编号:

MFCD00040484

PubChem化学物质编号:

57647769

NACRES:

NA.22

检测方案

≥98% (sum of isomers, GC)

形式

solid

组成

2-BHA, ≤10% GC
3-BHA, ≥90% GC

杂质

≤1% 4-hydroxyanisole

灼烧残渣

≤0.05%

mp

48-63 °C

溶解性

ethanol: soluble 1 g/10 mL, clear, colorless to faint yellow or tan

SMILES string

COc1ccc(O)c(c1)C(C)(C)C

InChI

1S/C11H16O2/c1-11(2,3)9-7-8(13-4)5-6-10(9)12/h5-7,12H,1-4H3

InChI key

MRBKEAMVRSLQPH-UHFFFAOYSA-N

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一般描述

研究了 3--叔 -丁基-4-羟基苯甲醚在酞菁镍（作为电子媒介体）修饰的聚合物电极上的伏安行为。

危险分类

Aquatic Chronic 2

储存分类代码

11 - Combustible Solids

WGK

WGK 2

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

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Voltammetric determination of the phenolic antioxidants 3-tert-butyl-4-hydroxyanisole and tert-butylhydroquinone at a polypyrrole electrode modified with a nickel phthalocyanine complex.

C de la Fuente et al.

Talanta, 49(2), 441-452 (2008-10-31)

The voltammetric behaviour of the antioxidants 3-tert-butyl-4-hydroxyanisole (BHA) and tert-butylhydroquinone (TBHQ), at a polymer electrode modified with nickel phthalocyanine as electron mediator, is described, and an electroanalytical method for the determination of these antioxidants based on their electrochemical oxidation on

Mutagenicity of 3-tert-butyl-4-hydroxyanisole (BHA) and its metabolites in short-term tests in vitro.

A Matsuoka et al.

Mutation research, 241(2), 125-132 (1990-06-01)

The mutagenicity of 3-tert-butyl-4-hydroxyanisole (BHA) and its metabolites was investigated in the reverse mutation assay using S. typhimurium strains and the chromosomal aberration test in vitro using a Chinese hamster fibroblast cell line, CHL. BHA, tert-butylhydroquinone (BHQ), tert-butylquinone (BQ) and

Metabolism of 3-tert-butyl-4-hydroxyanisole by horseradish peroxidase and hydrogen peroxide.

K Tajima et al.

Drug metabolism and disposition: the biological fate of chemicals, 20(6), 816-820 (1992-11-01)

3-Tert-butyl-4-hydroxyanisole (3-BHA) was metabolized in the presence of horseradish peroxidase and hydrogen peroxide to 2-tert-butyl-p-benzoquinone (TBQ), 2,3-epoxy-5-tert-butyl-1,4-benzoquinone (TBQ-epoxide), and two known dimers. The formation of TBQ from 3-BHA required both horseradish peroxidase and hydrogen peroxide. When 2.5 mM 3-BHA was

Induction of oxidative DNA damage and early lesions in rat gastro-intestinal epithelium in relation to prostaglandin H synthase-mediated metabolism of butylated hydroxyanisole.

P A Schilderman et al.

Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 33(2), 99-109 (1995-02-01)

The effect of metabolic activation of the food additive 3-tert-butyl-4-hydroxyanisole (BHA) by prostaglandin H synthase on the gastro-intestinal cell proliferation was determined by studies of the nature and the time dependency of early lesions in the forestomach, glandular stomach and

Glutathione conjugates of tert-butyl-hydroquinone, a metabolite of the urinary tract tumor promoter 3-tert-butyl-hydroxyanisole, are toxic to kidney and bladder.

M M Peters et al.

Cancer research, 56(5), 1006-1011 (1996-03-01)

3-tert-Butyl-4-hydroxyanisole and tert-butyl-hydroquinone (TBHQ) are antioxidants known to promote renal and bladder carcinogenesis in the rat, although the mechanisms of these effects are unclear. Because glutathione (GSH) conjugates of a variety of hydroquinones are nephrotoxic, and because 2-tert-butyl-5-(glutathion-S-yl)hydroquinone [5-(GSyl)TBHQ], 2-tert-butyl-6-(glutathion-S-yl)hydroquinone

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