20437
叔丁氧基(氯)二苯基硅烷
≥97.0% (GC)
别名:
叔丁氧基-二苯基氯硅烷
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关于此项目
经验公式（希尔记法）:
C16H19ClOSi
化学文摘社编号:
分子量:
290.86
PubChem Substance ID:
UNSPSC Code:
12352002
Beilstein/REAXYS Number:
5037778
MDL number:
assay
≥97.0% (GC)
contains
~0.5% CaCO3 as stabilizer
refractive index
n20/D 1.539
bp
130-135 °C/0.1 mmHg
density
1.076 g/mL at 20 °C (lit.)
storage temp.
−20°C
SMILES string
CC(C)(C)O[Si](Cl)(c1ccccc1)c2ccccc2
InChI
1S/C16H19ClOSi/c1-16(2,3)18-19(17,14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3
InChI key
MSZDOMFSWXWKTK-UHFFFAOYSA-N
Other Notes
引入新的醇保护基团的试剂；这类醚对酸水解反应的稳定性比对应的 TBDMS 醚高大约 10 倍，被 TBFA 裂解的容易程度比对应的 TBDMS 醚高大约 25 倍
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
132.8 °F - closed cup
flash_point_c
56 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
M. Grotli et al.
Journal of the Chemical Society. Chemical Communications, 495-495 (1995)
Gillard, J.W., et al.
The Journal of Organic Chemistry, 53, 2602-2602 (1988)