InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
InChI
1S/Pd
SMILES string
[Pd]
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Application
Palladium black can be used as a catalyst with a high surface area of ~47 m2g−1 in a variety of sustainable applications. It can be used as an anode catalyst that shows good performance and can be used in polymer exchange membrane (PEM) based fuel cells. It can also be used as an alternative catalyst to carbon-supported palladium for the hydrogenolysis reactions.
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
The behavior of palladium catalysts in direct formic acid fuel cells
Zhu Y, et al.
Journal of Power Sources, 139(1-2), 15-20 (2005)
Palladium black as model catalyst in the hydrogenolysis of CCl2F2 (CFC-12) into CH2F2 (HFC-32)
Van de Sandt E, et al.
Applied Catalysis A: General, 155(1), 59-73 (1997)
Freestanding palladium nanosheets with plasmonic and catalytic properties
Huang X, et al.
Nature Nanotechnology, 6(1), 28-28 (2011)
Xuxing Chen et al.
Organic & biomolecular chemistry, 11(16), 2582-2585 (2013-03-19)
A one-pot two-step synthesis of versatile indenones has been developed. This palladium(II)-catalyzed transformation involves generation and condensation of ortho-functionalized 1,2-benzils from 2-(2-arylethynylphenyl)acetonitriles using Ph2SO as the oxidant. The resulting 3-cyanoindenones can be converted to various valuable molecules.
Meifang Zheng et al.
Organic letters, 15(8), 1838-1841 (2013-04-02)
Palladium-catalyzed oxidative difunctionalization of enol ethers with 1,3-dicarbonyl compounds to construct trisubstituted furans in one step under mild conditions is described. The reaction is thought to proceed through a C-C bond formation along with a C-O bond closing the ring
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