213306
苯基乙烯基亚砜
95%
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关于此项目
线性分子式:
C6H5SOCH=CH2
化学文摘社编号:
分子量:
152.21
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
243-831-6
Beilstein/REAXYS Number:
2039218
MDL number:
Assay:
95%
Form:
liquid
Quality Segment
assay
95%
form
liquid
refractive index
n20/D 1.585 (lit.)
bp
93-95 °C/0.2 mmHg (lit.)
density
1.139 g/mL at 25 °C (lit.)
functional group
sulfoxide
storage temp.
2-8°C
SMILES string
C=CS(=O)c1ccccc1
InChI
1S/C8H8OS/c1-2-10(9)8-6-4-3-5-7-8/h2-7H,1H2
InChI key
MZMJHXFYLRTLQX-UHFFFAOYSA-N
Gene Information
human ... LOC129293(129293)
General description
Phenyl vinyl sulfoxide reacts with lithium enolates of ketones at -78°C in THF to yield bicyclo[n.2.0]alkan-1-ols. It also reacts with in situ generated (dialkylamino)magnesium reagent to yield symmetrical β-(dialkylamino)dithioacetals. It participates as an acetylene equivalent in Diels-Alder reactions.
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)