213535
2,4-二氯-6-甲氧基-1,3,5-三嗪
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关于此项目
经验公式（希尔记法）:
C4H3Cl2N3O
化学文摘社编号:
分子量:
179.99
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
222-863-4
MDL number:
InChI key
JKAPWXKZLYJQJJ-UHFFFAOYSA-N
InChI
1S/C4H3Cl2N3O/c1-10-4-8-2(5)7-3(6)9-4/h1H3
SMILES string
COc1nc(Cl)nc(Cl)n1
bp
132-134 °C/49 mmHg (lit.)
mp
86-88 °C (lit.)
functional group
chloro
Quality Level
Application
2,4-Dichloro-6-methoxy-1,3,5-triazine was used as reagent in radioimmunoassay for D-Ala2-Dermorphin, a natural peptide extracted from amphibian skin. It was also used in the preparation of:
- α-cyclodextrin [2]-rotaxanes
- substituted s-triazines
- series of chiral derivatizing reagents
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
H Brückner et al.
Journal of chromatography. A, 998(1-2), 73-82 (2003-07-17)
A series of chiral derivatizing reagents (CDRs) was synthesized by nucleophilic replacement of one chlorine atom in cyanuric chloride (2,4,6-trichloro-1,3,5-triazine; s-triazine) by alkoxy (methoxy, butoxy, 1,1,1-trifluoroethoxy) or aryloxy groups (phenoxy, nitrophenoxy, phenylphenoxy, 4-methylcoumaryloxy), and displacement of a second chlorine by
Ryan E Dawson et al.
Organic & biomolecular chemistry, 6(10), 1814-1821 (2008-05-03)
Ten alpha-cyclodextrin [2]-rotaxanes have been prepared with alkane-, stilbene- and azobenzene-based axles, capped through nucleophilic substitution of either 2-chloro-4,6-dimethoxy-1,3,5-triazine or 2,4-dichloro-6-methoxy-1,3,5-triazine in aqueous solution, followed by further substitution of the remaining triazinyl chlorine in some cases when the latter capping
L Negri et al.
Peptides, 2 Suppl 2, 45-49 (1981-01-01)
A selective RIA for D-Ala2-Dermorphin (Der), a natural peptide extracted from amphibian skin, has been developed using an antibody raised in rabbits against Der which has been coupled to BSA through its phenolic hydroxyl groups of tyrosine residues with 2,4-Dichloro-6-methoxy-1,3,5-triazine.
Recent applications of 2, 4, 6-trichloro-1, 3, 5-triazine and its derivatives in organic synthesis.
Blotny G.
Tetrahedron, 62(41), 9507-9522 (2006)
Tatsuki Nakano et al.
Analytica chimica acta, 880, 145-151 (2015-06-21)
In this study, a novel pre-column excimer fluorescence derivatization reagent, 2-chloro-4-methoxy-6-(4-(pyren-4-yl)butoxy)-1,3,5-triazine (CMPT), was developed for polyamines, specifically histamine. By CMPT derivatization, the polyamines, histamine and tyramine were converted to polypyrene derivatives, and emitted intra-molecular excimer fluorescence at 475nm. This could
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