214027
1,2,3,4,5-五甲基环戊二烯
95%
别名:
1,2,3,4,5-五甲基-1,3-环戊二烯
登录 查看组织和合同定价。
选择尺寸
关于此项目
经验公式（希尔记法）:
C10H16
化学文摘社编号:
分子量:
136.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
223-743-4
Beilstein/REAXYS Number:
1849832
MDL number:
产品名称
1,2,3,4,5-五甲基环戊二烯, 95%
InChI key
WQIQNKQYEUMPBM-UHFFFAOYSA-N
InChI
1S/C10H16/c1-6-7(2)9(4)10(5)8(6)3/h6H,1-5H3
SMILES string
CC1C(C)=C(C)C(C)=C1C
assay
95%
refractive index
n20/D 1.474 (lit.)
bp
58 °C/13 mmHg (lit.)
density
0.87 g/mL at 25 °C (lit.)
Quality Level
正在寻找类似产品? 访问 产品对比指南
Application
1,2,3,4,5-五甲基环戊二烯用作：
- 五羰基铁中的金属有机溶剂蒸汽沉积中的生长调节剂化学品。
- 通过肟的中间体将醇催化转化为酰胺的“一锅法”铱中的配体。
- 合成[Cp*Rh(bpy)H2O]2+（Cp* = 五甲基环戊二烯基，bpy = 2,2′-联吡啶），它是 NADH 再生过程中的电子介质。
General description
研究了顺磁性内层金属富勒烯与 1，2，3，4，5-五甲基环戊二烯的 Diels-Alder 反应机理。报道了 1，2，3，4，5-五甲基环戊二烯的三步法大规模合成。用激光烧蚀质谱法研究了 1，2，3，4，5-五甲基环戊二烯 (HCp*) 在气相中与钯离子的反应。它与富含电子的烯烃发生自由基阳离子催化的环加成反应，生成 Diels-Alder 产物。
An improved synthesis of 1,2,3,4,5-pentamethylcyclopentadiene.
Kohl FX and Jutzi P.
Journal of Organometallic Chemistry, 243(1), 119-121 (1983)
Bio-inspired NADH regeneration by carbon nitride photocatalysis using diatom templates.
Liu J and Antonietti M.
Energy & Environmental Science, 6(5), 1486-1493 (2013)
Synth. React. Inorg. Met.-Org. Chem. , 24, 395-395 (1994)
The Aminium Salt and Photoinduced Electron Transfer Initiated Diels-Alder Cycloaddition of Electron-rich Allenes: Evidence for a Stepwise Mechanism and the Importance of Steric and Electronic Effects for the Reactivity of Distonic Radical Cation Intermediates.
Schmittel M, et al.
Chemistry (Weinheim An Der Bergstrasse, Germany), 2(8), 1031-1040 (1996)
Nathan A Owston et al.
Organic letters, 9(1), 73-75 (2006-12-29)
[reaction: see text] The iridium catalyst [Ir(Cp*)Cl2]2 is effective for the rearrangement of oximes to furnish amides. The reaction has been combined with catalytic transfer hydrogenation between an alcohol and alkene to allow the conversion of alcohols into amides in
商品
The Diels–Alder reaction is the reaction between a conjugated diene and an alkene (dienophile) to form unsaturated six-membered rings. It is also referred to as a cycloaddition.
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
联系客户支持