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Merck
CN

217344

三氯乙酰胺

99%

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线性分子式:
Cl3CCONH2
化学文摘社编号:
分子量:
162.40
EC Number:
209-849-3
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1754028
MDL number:
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InChI key

UPQQXPKAYZYUKO-UHFFFAOYSA-N

InChI

1S/C2H2Cl3NO/c3-2(4,5)1(6)7/h(H2,6,7)

SMILES string

NC(=O)C(Cl)(Cl)Cl

assay

99%

form

solid

bp

238-240 °C (lit.)

mp

139-141 °C (lit.)

General description

三氯乙酰胺是三氯乙腈的主要降解产物

Application

将三氯乙酰胺用于基于芯片的转录组学和基于一维质子核磁共振的代谢组学,探讨三氯乙酰胺含氮消毒副产物对小鼠的健康影响

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

存储类别

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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历史批次信息供参考:

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Zheng Liu et al.
Organic letters, 12(13), 2974-2977 (2010-06-04)
Stereocontrolled syntheses of alpha-C-GalCer (2) and its alpha-C-acetylenic analogue 6 were accomplished in high efficiency by a convergent construction strategy from 1-hexadecene and d-galactose. The key transformations include Sonogashira coupling, Sharpless asymmetric epoxidation, and Et(2)AlCl-catalyzed cyclization of an epoxytrichloroacetimidate to
A E Christina et al.
Carbohydrate research, 356, 282-287 (2012-03-16)
Reported is the gram-scale synthesis of tert-butyldiphenylsilyl 4-(N-benzyloxycarbonyl)-amino-2-azido-2,4,6-trideoxy-β-D-galactopyranoside, which represents an orthogonally protected 2,4-diamino-D-fucose building block, a common constituent of various zwitterionic polysaccharides. The building block has been synthesized from D-glucosamine in 19% overall yield over 14 steps, requiring 5
Chan Lan Chun et al.
Environmental science & technology, 41(5), 1615-1621 (2007-04-03)
Disinfection byproducts (DBPs) in drinking water flowing through corroded iron or steel pipes may encounter carbonate green rust (GR(CO32-)), a mixed Fe(II)/Fe(lll) hydroxide mineral and potent reductant. This research was performed to investigate the kinetics and pathways of the degradation
Ophélie Milhomme et al.
Carbohydrate research, 356, 115-131 (2012-02-24)
The synthesis of the anthrax tetrasaccharide, amenable for conjugation, has been envisaged by both [2+2] and [1+3] approaches from D-fucose and L-rhamnose. The successful route reported herein relies on a [1+3] strategy in which the 1,2-trans-glycosidic linkages have been secured
Jeffrey S Arnold et al.
Journal of the American Chemical Society, 134(20), 8380-8383 (2012-05-09)
The rhodium-catalyzed regio- and enantioselective amination of racemic tertiary allylic trichloroacetimidates with a variety of aniline nucleophiles is a direct and efficient route to chiral α,α-disubstituted allylic N-arylamines. We describe the first dynamic kinetic asymmetric transformations of racemic tertiary allylic

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