217344
三氯乙酰胺
99%
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关于此项目
线性分子式:
Cl3CCONH2
化学文摘社编号:
分子量:
162.40
EC Number:
209-849-3
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1754028
MDL number:
InChI key
UPQQXPKAYZYUKO-UHFFFAOYSA-N
InChI
1S/C2H2Cl3NO/c3-2(4,5)1(6)7/h(H2,6,7)
SMILES string
NC(=O)C(Cl)(Cl)Cl
assay
99%
form
solid
bp
238-240 °C (lit.)
mp
139-141 °C (lit.)
General description
三氯乙酰胺是三氯乙腈的主要降解产物 。
Application
将三氯乙酰胺用于基于芯片的转录组学和基于一维质子核磁共振的代谢组学，探讨三氯乙酰胺含氮消毒副产物对小鼠的健康影响 。
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Joseph J Topczewski et al.
Journal of the American Chemical Society, 133(48), 19318-19321 (2011-11-09)
A rapid allylic fluorination method utilizing trichloroacetimidates in conjunction with an iridium catalyst has been developed. The reaction is conducted at room temperature under ambient air and relies on Et(3)N·3HF reagent to provide branched allylic fluorides with complete regioselectivity. This
Peter J Meloncelli et al.
Carbohydrate research, 346(12), 1406-1426 (2011-05-03)
The ABO histo-blood group antigens are best known for their important roles in solid organ and bone marrow transplantation as well as transfusion medicine. Here we report the synthesis of the ABO type III and IV antigens with a 7-octen-1-yl
Nihan Celebi-Olçüm et al.
The Journal of organic chemistry, 74(18), 6944-6952 (2009-08-20)
Density functional theory calculations were used to investigate the [3,3]- and [1,3]-shifts of O-allylic trichloroacetimidates in the presence of cinchona alkaloids. Thermal [1,3]- and [3,3]-rearrangements proceed through concerted pseudopericyclic transition states to give the corresponding rearranged products. [1,3]-Rearrangement is catalyzed
Jeffrey S Arnold et al.
Chemical communications (Cambridge, England), 48(94), 11531-11533 (2012-10-24)
We report the chiral diene ligated rhodium-catalyzed dynamic kinetic asymmetric transformation (DYKAT) of racemic secondary allylic trichloroacetimidates with a variety of N-methyl anilines, providing allylic N-methyl arylamines in high yields, regioselectivity, and enantiomeric excess. The rhodium-catalyzed DYKAT method addresses limitations
Tatsuya Komori et al.
Carbohydrate research, 344(12), 1453-1463 (2009-06-30)
A first systematic synthesis of the glycan parts of the a-series gangliosides (GT1a, GD1a, and GM1) utilizing the newly developed N-Troc-protected GM3 and galactosaminyl building blocks is described. The key processes, including the assembly of the GM2 sequence and its
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