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线性分子式:
ClC6H4NO2
化学文摘社编号:
分子量:
157.55
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-496-1
Beilstein/REAXYS Number:
1907947
MDL number:
Assay:
98%
Form:
solid
InChI key
KMAQZIILEGKYQZ-UHFFFAOYSA-N
InChI
1S/C6H4ClNO2/c7-5-2-1-3-6(4-5)8(9)10/h1-4H
SMILES string
[O-][N+](=O)c1cccc(Cl)c1
assay
98%
form
solid
autoignition temp.
500 °F
bp
236 °C (lit.)
Quality Level
solubility
alcohol: freely soluble (hot)(lit.), alcohol: very slightly soluble(lit.), carbon disulfide: freely soluble(lit.), chloroform: freely soluble(lit.), diethyl ether: freely soluble(lit.), glacial acetic acid: freely soluble(lit.), water: insoluble(lit.)
density
1.534 g/mL at 25 °C (lit.)
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Application
1-Chloro-3-nitrobenzene was used in the preparation of aromatic azo compounds using gold (Au) nanoparticles supported on TiO2 as a catalyst. It was also used as surrogate standard to evaluate the removal of 2,4-dinitrotoluene from contaminated soils using enhanced electrokinetic remediation.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
255.2 °F
flash_point_c
124 °C
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
法规信息
危险化学品
此项目有
Cyclodextrin-enhanced extraction and removal of 2, 4-dinitrotoluene from contaminated soils.
Khodadoust AP, et al.
Environmental Engineering Science, 25(4), 615-626 (2008)
Violeta Simic-Milosevic et al.
Angewandte Chemie (International ed. in English), 48(22), 4061-4064 (2009-04-01)
Chirality chameleon: Inelastic electron tunneling manipulation can be used to change a single chloronitrobenzene (ClNB) molecule, randomly adsorbed on Au(111), into its desired enantiomeric form (r or l, see STM images and ball-and-stick representation) and to vary its rotational orientation.
[Hygienic study of the stability of methylnitrophos and pentachloronitrobenzene used in agriculture].
Sh T Atabaev et al.
Gigiena i sanitariia, (2)(2), 74-75 (1983-02-01)
Abdessamad Grirrane et al.
Nature protocols, 5(3), 429-438 (2010-03-06)
This protocol describes the aerobic oxidation of aromatic anilines to aromatic azo compounds using gold (Au) nanoparticles supported on TiO(2) as a catalyst. Yields above 98% are achieved under a few bars of oxygen pressure. It should be noted that
V Simic-Milosevic et al.
Physical review letters, 98(11), 116102-116102 (2007-05-16)
A scanning tunneling microscope operating at 5 K is used to induce the isomerization of single chloronitrobenzene molecules on Cu(111) and verify the reaction. The threshold voltage of (227+/-7) mV for this reaction is explained based on electron-induced vibrational heating.
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