Merck
CN

219533

Sigma-Aldrich

1-硝基-1-环己烯

99%

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Empirical Formula (Hill Notation):
C6H9NO2
CAS号:
分子量:
127.14
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

检测方案

99%

形式

liquid

折射率

n20/D 1.505 (lit.)

bp

66-68 °C/1.5 mmHg (lit.)

密度

1.127 g/mL at 25 °C (lit.)

储存温度

2-8°C

SMILES string

[O-][N+](=O)C1=CCCCC1

InChI

1S/C6H9NO2/c8-7(9)6-4-2-1-3-5-6/h4H,1-3,5H2

InChI key

DJBRXNRKYAWTBL-UHFFFAOYSA-N

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此商品
125431244414467030
1-Nitro-1-cyclohexene 99%

Sigma-Aldrich

219533

1-硝基-1-环己烯

Cyclohexene inhibitor-free, ReagentPlus®, 99%

Sigma-Aldrich

125431

环己烯

1-Heptyne 98%

Sigma-Aldrich

244414

1-庚炔

1-Cyclohexene-1-carboxaldehyde 97%

Sigma-Aldrich

467030

1-环己烯-1-甲醛

form

liquid

form

liquid

form

liquid

form

-

refractive index

n20/D 1.505 (lit.)

refractive index

n20/D 1.446 (lit.)

refractive index

n20/D 1.408 (lit.)

refractive index

-

bp

66-68 °C/1.5 mmHg (lit.)

bp

83 °C (lit.)

bp

99-100 °C (lit.)

bp

61 °C/10 mmHg (lit.)

density

1.127 g/mL at 25 °C (lit.)

density

0.811 g/mL at 25 °C (lit.)

density

0.733 g/mL at 25 °C (lit.)

density

0.966 g/mL at 25 °C (lit.)

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-

一般描述

1-硝基-1-环己烯的化学选择性氢化是由负载在TiO2或Fe2O3上的金纳米粒子所催化的

应用

1-硝基-1-环己烯可通过负载的金纳米粒子(Au/TiO2及Au/Fe2O3)所催化的化学选择性加氢用于制备取代苯胺

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

174.2 °F - closed cup

闪点(°C)

79 °C - closed cup


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Slide 1 of 1

1 of 1

Cyclohexene contains 100 ppm BHT as inhibitor, ≥99.0%

Sigma-Aldrich

29240

环己烯

Avelino Corma et al.
Science (New York, N.Y.), 313(5785), 332-334 (2006-07-22)
The selective reduction of a nitro group when other reducible functions are present is a difficult process that often requires stoichiometric amounts of reducing agents or, if H2 is used, the addition of soluble metals. Gold nanoparticles supported on TiO2
Avelino Corma et al.
Nature protocols, 1(6), 2590-2595 (2007-04-05)
A protocol for the chemoselective hydrogenation of nitro compounds to the corresponding anilines by means of supported gold catalysts is described. Nitro groups on different compounds--containing double bonds, carbonyl, nitrile or amide groups--have been successfully hydrogenated on supported gold nanoparticles
Fabian Niedermair et al.
Inorganic chemistry, 49(20), 9333-9342 (2010-09-16)
A series of π-extended phosphorescent palladium(II) and platinum(II) porphyrin complexes were synthesized, in which additional benzene rings are fused radially onto at least one of the four peripheral benzo groups. The photophysical properties of the metalloporphyrins palladium(II)-meso-tetra-(4-fluorophenyl)mononaphthotribenzoporphyrin (Pd1NF), cis-palladium(II)-meso-tetra-(4-fluorophenyl)dibenzodinaphthoporphyrin (Pd2NF)

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