产品名称
1-硝基-1-环己烯, 99%
InChI key
DJBRXNRKYAWTBL-UHFFFAOYSA-N
InChI
1S/C6H9NO2/c8-7(9)6-4-2-1-3-5-6/h4H,1-3,5H2
SMILES string
[O-][N+](=O)C1=CCCCC1
assay
99%
form
liquid
refractive index
n20/D 1.505 (lit.)
bp
66-68 °C/1.5 mmHg (lit.)
density
1.127 g/mL at 25 °C (lit.)
functional group
nitro
storage temp.
2-8°C
Quality Level
Application
1-硝基-1-环己烯可通过负载的金纳米粒子（Au/TiO2及Au/Fe2O3）所催化的化学选择性加氢用于制备取代苯胺。
General description
1-硝基-1-环己烯的化学选择性氢化是由负载在TiO2或Fe2O3上的金纳米粒子所催化的。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
Avelino Corma et al.
Science (New York, N.Y.), 313(5785), 332-334 (2006-07-22)
The selective reduction of a nitro group when other reducible functions are present is a difficult process that often requires stoichiometric amounts of reducing agents or, if H2 is used, the addition of soluble metals. Gold nanoparticles supported on TiO2
Avelino Corma et al.
Nature protocols, 1(6), 2590-2595 (2007-04-05)
A protocol for the chemoselective hydrogenation of nitro compounds to the corresponding anilines by means of supported gold catalysts is described. Nitro groups on different compounds--containing double bonds, carbonyl, nitrile or amide groups--have been successfully hydrogenated on supported gold nanoparticles
Fabian Niedermair et al.
Inorganic chemistry, 49(20), 9333-9342 (2010-09-16)
A series of π-extended phosphorescent palladium(II) and platinum(II) porphyrin complexes were synthesized, in which additional benzene rings are fused radially onto at least one of the four peripheral benzo groups. The photophysical properties of the metalloporphyrins palladium(II)-meso-tetra-(4-fluorophenyl)mononaphthotribenzoporphyrin (Pd1NF), cis-palladium(II)-meso-tetra-(4-fluorophenyl)dibenzodinaphthoporphyrin (Pd2NF)
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