22135
(+)-雪松醇
≥99.0% (sum of enantiomers, GC)
别名:
(1S,2R,5S,7R,8R)-2,6,6,8-四甲基三环[5.3.1.01.5]十一烷-8-醇
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关于此项目
经验公式（希尔记法）:
C15H26O
化学文摘社编号:
分子量:
222.37
UNSPSC Code:
12352212
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-035-6
Beilstein/REAXYS Number:
2206347
MDL number:
Assay:
≥99.0% (sum of enantiomers, GC)
Form:
solid
Quality Level
assay
≥99.0% (sum of enantiomers, GC)
form
solid
optical activity
[α]20/D +10.5±1°, c = 5% in chloroform
bp
273 °C (lit.)
mp
82-86 °C, 86-87 °C (lit.)
functional group
hydroxyl
SMILES string
C[C@@H]1CC[C@H]2C(C)(C)[C@H]3C[C@@]12CC[C@@]3(C)O
InChI
1S/C15H26O/c1-10-5-6-11-13(2,3)12-9-15(10,11)8-7-14(12,4)16/h10-12,16H,5-9H2,1-4H3/t10-,11+,12-,14-,15+/m1/s1
InChI key
SVURIXNDRWRAFU-OGMFBOKVSA-N
General description
（+）-雪松醇是α-雪松烯的结晶水合产物，雪松烯是雪松木油中发现的倍半萜烯。它可以用作化妆品，洗发水和肥皂中的香料成分，也可以用作非化妆品，例如清洁剂和洗涤剂。（±）雪松醇可以通过烷基环戊二烯的分子内Diels-Alder反应合成。
Application
（+）-雪松醇可用作在酸催化剂存在下使用乙酸酐乙酰化制备乙酸雪松酯的起始原料。它也可以作为通过选择性C-H键官能化全合成稀有八角倍半萜（+）-假茴香苷的前体掺入。
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存储类别
11 - Combustible Solids
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Catalytic acetylation of (+)-cedrol with heterogeneous catalyst H2SO4/SiO2 under solvent free conditions
Elvia R, et al.
Chemical Intermediates, 1(4), 196-201 (2015)
Total synthesis of (.+-.)-cedrol and (.+-.)-cedrene via an intramolecular Diels-Alder reaction
Breitholle EG and Fallis AG
The Journal of Organic Chemistry, 43(10), 1964-1968 (1978)
Kevin Hung et al.
Journal of the American Chemical Society, 138(51), 16616-16619 (2016-12-15)
Illicium sesquiterpenes have been the subject of numerous synthetic efforts due to their ornate and highly oxidized structures as well as significant biological activities. Herein we report the first chemical synthesis of (+)-pseudoanisatin from the abundant feedstock chemical cedrol (∼$50
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 22135-5G | 04061833347928 |