232025
4-(三氟甲基)苄醇
98%
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关于此项目
线性分子式:
CF3C6H4CH2OH
化学文摘社编号:
分子量:
176.14
EC Number:
206-494-6
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1450174
MDL number:
InChI key
MOOUWXDQAUXZRG-UHFFFAOYSA-N
InChI
1S/C8H7F3O/c9-8(10,11)7-3-1-6(5-12)2-4-7/h1-4,12H,5H2
SMILES string
OCc1ccc(cc1)C(F)(F)F
assay
98%
refractive index
n20/D 1.459 (lit.)
bp
78-80 °C/4 mmHg (lit.)
density
1.286 g/mL at 25 °C (lit.)
General description
Photocatalytic oxidation of 4-(trifluoromethyl)benzyl alcohol to corresponding aldehydes on TiO2 photocatalyst under O2 atmosphere has been reported.
Application
用于（例如）磷酰甲酸酯药物前体和水合铬(IV)的动力学研究的试剂。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
213.8 °F - closed cup
flash_point_c
101 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Journal of the American Chemical Society, 114, 4205-4205 (1992)
Selective photocatalytic oxidation of benzyl alcohol and its derivatives into corresponding aldehydes by molecular oxygen on titanium dioxide under visible light irradiation.
Higashimoto S, et al.
J. Catal., 266(2), 279-285 (2009)
J. Chem. Soc. Perkin Trans. II, 1145-1145 (1992)
One-pot synthesis of fluorine-containing alkenes from in situ-generated stabilized phosphorus ylides.
Pakravan P, et al.
Phosphorus, Sulfur, and Silicon and the Related Elements, 182(3), 545-549 (2007)
D C Anderson et al.
Biochemistry, 19(24), 5486-5493 (1980-11-25)
The interactions of horse liver alcohol dehydrogenase (LADH) with the rho-trifluoromethyl derivatives of benzyl alcohol, benzaldehyde, and benzoic acid have been investigated by use of 19F nuclear magnetic resonance. The aldehyde and alcohol are good substrates for the enzyme and
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