方案
97%
表单
liquid
折射率
n20/D 1.452 (lit.)
沸点
137-138 °C/50 mmHg (lit.)
密度
1.573 g/mL at 25 °C (lit.)
SMILES字符串
CCC(Br)C(=O)OC
InChI
1S/C5H9BrO2/c1-3-4(6)5(7)8-2/h4H,3H2,1-2H3
InChI key
UFQQDNMQADCHGH-UHFFFAOYSA-N
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应用
Methyl 2-bromobutyrate has been employed as reagent in the synthesis of:
- racemic indene ester via Reformatsky reaction with 5-methoxy-1-indanone
- (E)-2-methoxymethylene-butyric acid methyl ester via Reformatsky reaction with α,α-dichloromethyl methyl ether in the presence of zinc dust
- (E)-2-methoxymethylene-butyryl chloride
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
154.4 °F - closed cup
闪点(°C)
68 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
Thomas Hjelmgaard et al.
Organic & biomolecular chemistry, 4(9), 1796-1805 (2006-04-25)
This paper describes the development of a straightforward experimental protocol for copper-mediated cross-coupling of amino acid derived beta-amido-alkylzinc iodides 1 and 3 with a range of acid chlorides. The present method uses CuCN.2LiCl as the copper source and for organozinc
An efficient enantioselective synthesis of an indane acetic acid derivative: methyl (2S)-2-[(1S)-5-hydroxy-2, 3-dihydro-1H-inden-1-yl] butanoate.
Zhang M, et al.
Tetrahedron Asymmetry, 14(22), 3447-3453 (2003)
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