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Merck
CN

239798

1,3-二氧戊环

≥99.5%

别名:

乙二醇亚甲基醚, 乙二醇缩甲醛

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关于此项目

经验公式(希尔记法):
C3H6O2
化学文摘社编号:
分子量:
74.08
PubChem Substance ID:
UNSPSC Code:
12352200
Beilstein/REAXYS Number:
102453
MDL number:
Assay:
≥99.5%
Bp:
75-76 °C/1.013 hPa
Vapor pressure:
70 mmHg ( 20 °C)
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vapor density

2.6 (vs air)

vapor pressure

70 mmHg ( 20 °C)

assay

≥99.5%

autoignition temp.

525 °F

contains

75 ppm BHT as inhibitor

refractive index

n20/D 1.401 (lit.)

bp

75-76 °C/1.013 hPa

mp

−95 °C (lit.)

density

1.06 g/mL at 25 °C (lit.)

SMILES string

C1COCO1

InChI

1S/C3H6O2/c1-2-5-3-4-1/h1-3H2

InChI key

WNXJIVFYUVYPPR-UHFFFAOYSA-N



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Benito Alcaide et al.
The Journal of organic chemistry, 78(18), 8956-8965 (2013-09-07)
The gold-catalyzed preparation of 2-azetidinone-fused oxacycles was accomplished from β-lactam-linked enynes through heterocyclization reaction taking advantage of the acetonide pendant group. While the synthesis of fused tetrahydrofuran-β-lactams from 1,3-enynes could be considered as an unusual metal-catalyzed cyclization of enynols, α-alkoxy
Matthias Schmidt et al.
Bioorganic & medicinal chemistry, 15(6), 2283-2297 (2007-02-06)
Multidrug resistance (MDR) to antitumor agents represents a major obstacle to a successful chemotherapy of cancer. Overexpression of P-glycoprotein (p-gp) seems to be the major factor responsible for MDR. A large number of chemically unrelated compounds are known to interact
Benjamin L Wegenhart et al.
Inorganic chemistry, 49(11), 4741-4743 (2010-05-06)
Low catalyst loading of a cationic oxorhenium(V) oxazoline complex, [2-(2'-hydroxyphenyl)-2-oxazolinato(-2)]oxorhenium(v), condenses diols and aldehydes to give 1,3-dioxolanes in excellent yields under neat conditions and reasonably mild temperatures. The reaction is applicable to biomass-derived furfural and glycerol. The resulting cyclic acetals