241814
三叔丁氧基氢化铝锂 溶液
1.0 M in THF
别名:
LTTBA, 三-叔-丁氧基氢化铝锂, 氢化三叔丁醇铝酸锂
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关于此项目
线性分子式:
LiAlH[OC(CH3)3]3
化学文摘社编号:
分子量:
254.27
UNSPSC Code:
12352000
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5796791
Form:
liquid
form
liquid
Quality Level
reaction suitability
reagent type: reductant
concentration
1.0 M in THF
density
0.904 g/mL at 25 °C
SMILES string
[Li+].CC(C)(C)O[AlH-](OC(C)(C)C)OC(C)(C)C
InChI
1S/3C4H9O.Al.Li.H/c3*1-4(2,3)5;;;/h3*1-3H3;;;/q3*-1;+2;+1;
InChI key
BYBIDFZFKATBFH-UHFFFAOYSA-N
General description
三叔丁 氧基氢化铝锂是一种温和的还原剂 ，主要用于酮的选择性还原。
Application
- 还原剂
signalword
Danger
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
target_organs
Central nervous system, Respiratory system
法规信息
危险化学品
此项目有
Synthesis of an enantiomerically pure intermediate containing the CD substructure of taxol.
Isaacs RC, et al.
The Journal of Organic Chemistry, 58(15), 3938-3941 (1993)
Stereoselectivity of lithium tri-tert-butoxyaluminum hydride.
Ashby EC, et al.
The Journal of Organic Chemistry, 36(1), 197-199 (1971)
The use of 4, 4-disubstituted nopinones for natural-product synthesis. Synthesis of elemanoid sesquiterpenes.
Kato M, et al.
The Journal of Organic Chemistry, 56(25), 7071-7076 (1991)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 241814-800ML | 04061838125873 |
| 241814-100ML | 04061825471686 |