24377
2-氯-1,3-二甲基咪唑鎓四氟硼酸盐
≥95.0% (AT)
别名:
CIB
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关于此项目
经验公式（希尔记法）:
C5H10BClF4N2
化学文摘社编号:
分子量:
220.40
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C5H10ClN2.BF4/c1-7-3-4-8(2)5(7)6;2-1(3,4)5/h3-4H2,1-2H3;/q+1;-1
SMILES string
F[B-](F)(F)F.CN1CC[N+](C)=C1Cl
InChI key
UPLXKEIRISBKRM-UHFFFAOYSA-N
assay
≥95.0% (AT)
form
solid
reaction suitability
reaction type: Coupling Reactions
mp
175-177 °C (lit.), 175-178 °C
solubility
acetonitrile: 0.1 g/mL, clear
application(s)
peptide synthesis
storage temp.
2-8°C
Application
Reagent for:
Esterification and peptide coupling of sterically hindered amino acids
Preparation of efficient diazo-transfer reagents
Oxidative insertion for palladium and nickel catalyst synthesis
Preparation of catalysts for use in coupling reactions
Esterification and peptide coupling of sterically hindered amino acids
Preparation of efficient diazo-transfer reagents
Oxidative insertion for palladium and nickel catalyst synthesis
Preparation of catalysts for use in coupling reactions
Other Notes
用于 C-端氨基酸在无外消旋作用下结合到王氏树脂上的酯化反应以及 α,α-二甲基氨基酸的偶联反应的试剂；制备一种新型偶联试剂，苯并三唑-1-基氧基衍生物
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
K. Akaji et al.
Proc. 22nd Eur. Pept. Symp.: Peptides 1992, 220-220 (1992)
Tetrahedron Letters, 33, 3177-3177 (1992)
Y. Kiso et al.
Chemical & Pharmaceutical Bulletin, 38, 270-270 (1990)
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