246565
2-吡啶基乙腈
99%
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经验公式（希尔记法）:
C7H6N2
化学文摘社编号:
分子量:
118.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-364-6
Beilstein/REAXYS Number:
111215
MDL number:
Assay:
99%
产品名称
2-吡啶基乙腈, 99%
InChI key
UKVQBONVSSLJBB-UHFFFAOYSA-N
InChI
1S/C7H6N2/c8-5-4-7-3-1-2-6-9-7/h1-3,6H,4H2
SMILES string
N#CCc1ccccn1
assay
99%
refractive index
n20/D 1.525 (lit.)
bp
76-77 °C/2 mmHg (lit.)
density
1.059 g/mL at 25 °C (lit.)
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General description
2-吡啶乙腈与芳香重氮盐偶联生成芳基腙。它还与活性丙二酸酯缩合生成1-氰基-3-取代的2-羟基喹啉-4-酮。2-吡啶乙腈与热乙酸酐的酰化反应已有报告。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
201.2 °F - closed cup
flash_point_c
94 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
F S Soliman et al.
Die Pharmazie, 32(5), 278-279 (1977-05-01)
Active malonic esters condense with 2-pyridylacetonitrile giving 1-cyano-3-substituted 2-hydroxyquinolizin-4-ones. Catalytic hydrogenation of the resulting products led to the corresponding 1-cyano-3-substituted-2-hydroxy-6.7.8.9-tetrahydroquinolizin-4-ones. On the other hand, condensation of the active malonic esters with beta-aminocrotononitrile afforded 5-cyano-3-substituted-4-hydroxy-6-methylpyridine-2-ones. The IR and NMR data are
Mariam Abdullah Al-Sheikh et al.
Molecules (Basel, Switzerland), 14(11), 4406-4413 (2009-11-20)
2-Pyridylacetonitrile (1) couples with aromatic diazonium salts to yield arylhydrazones 2a-c, that were shown to exist in the syn-form 2 rather than the anti-form 4. Compounds 2a,c reacted with hydroxylamine in refluxing DMF to yield the interesting 1,2,3-triazolylpyridines 6. Attempts
Acylation and other reactions of 2-and 4-pyridylacetonitrile.
Gutsche CD and Voges HD.
The Journal of Organic Chemistry, 32(9), 2685-2689 (1969)
Amit N Pandya et al.
Tetrahedron letters, 55(50), 6922-6924 (2014-12-17)
An efficient strategy for the synthesis of indolizines from readily available starting materials via oxidative C-H functionalization and
Masazumi Tamura et al.
Nature communications, 6, 8580-8580 (2015-10-06)
Multidentate materials formed by simply mixing heterogeneous and homogeneous components are promising for construction of versatile active sites on the surface of heterogeneous compounds, however, to the best of our knowledge, there are no reports on such materials. Self-assembly of
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