247057
四丁基高碘酸铵
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线性分子式:
(CH3CH2CH2CH2)4N(IO4)
化学文摘社编号:
分子量:
433.37
UNSPSC Code:
12352302
NACRES:
NA.23
PubChem Substance ID:
EC Number:
265-614-5
Beilstein/REAXYS Number:
4621593
MDL number:
Form:
solid
InChI key
PYVXLMQALOZKES-UHFFFAOYSA-M
InChI
1S/C16H36N.HIO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
SMILES string
[O-]I(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
form
solid
reaction suitability
reagent type: oxidant
concentration
29.3% iodine (titration)
mp
175 °C (dec.) (lit.)
Quality Level
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Application
Tetrabutylammonium (meta)periodate (DCM) can be oxidated for the synthesis of aryl nitroso derivatives. It can also be used in the formation of an ionic liquid for the synthesis of aromatic carboxylic acids.
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
5.1B - Oxidizing hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Efficient synthesis of aromatic carboxylic acids from aryl ketones in ionic liquid
Lee JC and Lee J
Synthetic Communications, 36(8), 1071-1074 (2006)
Study of Enantioselective Catalysis of Nitroso-Diels-Alder Reaction on Solid Support
Kratka L and Hlavavc J
ChemistrySelect, 2(14), 3987-3992 (2017)
Carmen E Castillo et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 27(15), 4946-4954 (2020-12-23)
Oxoiron(IV) complexes bearing tetradentate ligands have been extensively studied as models for the active oxidants in non-heme iron-dependent enzymes. These species are commonly generated by oxidation of their ferrous precursors. The mechanisms of these reactions have seldom been investigated. In
Michelle L Ingalsbe et al.
Bioorganic & medicinal chemistry letters, 19(17), 4984-4987 (2009-08-08)
Due to the increasing number of strains of drug-resistant bacteria, the development of new antibiotics has become increasingly important. The antibacterial properties of quaternary amines and their derivatives on both Gram-positive and Gram-negative bacteria are well known. However, an encompassing
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