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Merck
CN

247278

4,4′-二氨基二苯醚

purified by sublimation, ≥99%

别名:

4,4′-二氨基二苯基醚, 4-氨基苯基醚

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关于此项目

线性分子式:
O(C6H4NH2)2
化学文摘社编号:
分子量:
200.24
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-977-0
Beilstein/REAXYS Number:
475735
MDL number:
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InChI key

HLBLWEWZXPIGSM-UHFFFAOYSA-N

InChI

1S/C12H12N2O/c13-9-1-5-11(6-2-9)15-12-7-3-10(14)4-8-12/h1-8H,13-14H2

SMILES string

Nc1ccc(Oc2ccc(N)cc2)cc1

vapor pressure

10 mmHg ( 240 °C)

assay

≥99%

form

solid

purified by

sublimation

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General description

4,4′-Oxydianiline was used to tailor the properties of octa(aminophenyl)-silsesquioxane cross-linked polyimide aerogels. It was also used in the preparation of novel polyimide hybrid nanocomposite containing polyhedral oligomeric silsesquioxane.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Muta. 1B - Repr. 2 - Skin Sens. 1

存储类别

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 3

flash_point_f

426.2 °F - closed cup

flash_point_c

219 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Haiquan Guo et al.
ACS applied materials & interfaces, 4(10), 5422-5429 (2012-09-08)
Combinations of rigid and flexible aromatic diamines were used to tailor the properties of octa(aminophenyl)-silsesquioxane (OAPS) cross-linked polyimide aerogels. 2,2'-Dimethylbenzidine (DMBZ) or p-phenylenediamine (PPDA) was used in combination with the more-flexible diamine, 4,4'-oxydianiline (ODA). The amount of rigid diamine was
Shuwang Duo et al.
Journal of nanoscience and nanotechnology, 13(2), 1356-1359 (2013-05-08)
A novel polyimide (PI) hybrid nanocomposite containing polyhedral oligomeric silsesquioxane (POSS) had been prepared by copolymerization of trisilanolphenyl-POSS, 4,4'-oxydianiline (ODA), and pyromellitic dianhydride (PMDA). The AO resistance of these PI/POSS hybrid films was tested in the ground-based AO simulation facility.
N M Vasilenko et al.
Gigiena truda i professional'nye zabolevaniia, (10)(10), 26-28 (1991-01-01)
The article contains experimental data on the morphofunctional state of gonads in male rats after chronic inhalation of diamine P, and on the state of embryogenesis after inhalant introduction of diamine P into pregnant rats in threshold-level concentrations. Results of
K Tanaka et al.
Mutation research, 143(1-2), 11-15 (1985-05-01)
3 epoxy-resin hardeners, 4,4'-diaminodiphenyl ether (DDE), 4,4'-diaminodiphenylmethane (DDM), and 4,4'-diaminodiphenylsulfone (DDS), and their N-acetyl and N,N'-diacetyl derivatives were examined for their mutagenicity using Salmonella typhimurium TA98 and TA100 as the tester stains and an S9 mix containing a rat-liver 9000
E K Weisburger et al.
Journal of the National Cancer Institute, 72(6), 1457-1463 (1984-06-01)
Feeding 4,4'-methylenebis(N,N-dimethyl)benzenamine [CAS: 101-61-1; 4,4'-methylenebis(N,N-dimethylaniline)] to inbred F344 rats increased the incidence of thyroid lesions (hyperplasia, adenomas, and carcinomas) in both sexes, especially in the female rats. 4,4'- Oxydianiline (CAS: 101-80-4) in the diet increased adenomas and carcinomas in the

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