Quality Level
assay
97%
form
liquid
refractive index
n20/D 1.562 (lit.)
bp
246-247 °C/714 mmHg (lit.)
density
1.026 g/mL at 25 °C (lit.)
SMILES string
NC1CCCc2ccccc12
InChI
1S/C10H13N/c11-10-7-3-5-8-4-1-2-6-9(8)10/h1-2,4,6,10H,3,5,7,11H2
InChI key
JRZGPXSSNPTNMA-UHFFFAOYSA-N
General description
(R)-1,2,3,4-Tetrahydro-1-naphthylamine is an efficient reagent for iodocyclization of 4-aryl-4-pentenoic acids.
Application
1,2,3,4-Tetrahydro-1-naphthylamine has been used in the preparation of new chiral phosphine-aminophosphine ligands.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Modular Phosphine-Aminophosphine Ligands Based on Chiral 1, 2, 3, 4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations.
Qiu M, et al.
Advanced Synthesis & Catalysis, 350(17), 2683-2689 (2008)
Jürgen Haas et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 11(19), 5777-5785 (2005-07-23)
Lactonizations are important steps in many synthetic sequences. Substrate-controlled reactions that use chiral auxiliaries or chiral alkenes have already been studied in depth. This study focuses on stereoselective reagent-controlled iodolactonizations, by application of a new method that uses complexes of
Noelia Madroñal et al.
Nature communications, 7, 10923-10923 (2016-03-19)
The hippocampus is critical for the acquisition and retrieval of episodic and contextual memories. Lesions of the dentate gyrus, a principal input of the hippocampus, block memory acquisition, but it remains unclear whether this region also plays a role in
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 247820-5G | 04061825919263 |
| 247820-25G | 04061825919256 |