248193
3′-氯苯丙酮
98%
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关于此项目
线性分子式:
ClC6H4COC2H5
化学文摘社编号:
分子量:
168.62
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
252-242-3
MDL number:
产品名称
3′-氯苯丙酮, 98%
InChI key
PQWGFUFROKIJBO-UHFFFAOYSA-N
InChI
1S/C9H9ClO/c1-2-9(11)7-4-3-5-8(10)6-7/h3-6H,2H2,1H3
SMILES string
CCC(=O)c1cccc(Cl)c1
assay
98%
form
solid
bp
124 °C/14 mmHg (lit.)
mp
45-47 °C (lit.)
functional group
chloro
ketone
Quality Level
Application
3′-氯代苯丙酮可用作合成以下物质的反应物：
- 通过生物催化不对称还原法制备的（S）-3-氯-1-苯基丙醇
- 在二羟基双磺酰胺配体存在的情况下通过与二苯基锌的苯基化作用制备的1-(3-氯苯基)-1-苯基-1-丙醇。
- 选择性5-羟色胺再摄取抑制剂(S)-达泊西汀。
General description
溶剂和温度对3′-氯苯乙酮苯基化产率和对映选择性的影响已被研究。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Enhancing asymmetric reduction of 3-chloropropiophenone with immobilized Acetobacter sp. CCTCC M209061 cells by using deep eutectic solvents as cosolvents
Xu Pei, et al.
ACS sustainable chemistry & engineering, 3(4), 718-724 (2015)
Asymmetric total synthesis of (S)-dapoxetine
Kim Sun Joo, et al.
Tetrahedron Letters, 53(28), 3680-3682 (2012)
Asymmetric reduction of (S)-3-chloro-1-phenylpropanol from 3-chloropropiophenone by preheated immobilized Candida utilis
Yang Gen-Sheng, et al.
Biotechnology Letters, 12, 1879-1883 (2009)
Celina García et al.
Organic letters, 5(20), 3641-3644 (2003-09-26)
[reaction: see text] The catalytic asymmetric addition of phenyl groups from diphenylzinc to ketones is reported. The catalyst, generated from a dihydroxy bis(sulfonamide) ligand and titanium tetraisopropoxide, gives good to excellent enantioselectivities with a range of substrates.
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