25205
氯甲基苯亚砜
≥97.0%
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关于此项目
线性分子式:
C6H5SOCH2Cl
化学文摘社编号:
分子量:
174.65
EC Number:
230-580-2
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
1617664
MDL number:
InChI key
WCUSVVDFUIMPKY-UHFFFAOYSA-N
InChI
1S/C7H7ClOS/c8-6-10(9)7-4-2-1-3-5-7/h1-5H,6H2
SMILES string
ClCS(=O)c1ccccc1
assay
≥97.0%
form
solid
bp
109-111 °C/0.01 mmHg
mp
33-35 °C
storage temp.
−20°C
General description
Chloromethyl phenyl sulfoxide has synthetic potential and exhibits unusual stereochemical specificity. Stereospecific hydroxyalkylation of chloromethyl phenyl sulfoxide has been investigated.
Application
Chloromethyl phenyl sulfoxide has been used in the preparation of:
- 1-chloroalkyl sulfoxides
- starting material for the synthesis alkyl sulfoxides and thiol ester acyl anion equivalent
Other Notes
合成烷基亚砜的原料；硫羟酸酯的酰基阴离子等价物
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Stereospecific hydroxyalkylation of chloromethyl phenyl sulfoxide.
Durst T.
Journal of the American Chemical Society, 91(4), 1034-1035 (1969)
K.M. Moore et al.
The Journal of Organic Chemistry, 43, 2713-2713 (1978)
Tsuyoshi Satoh
Chemical record (New York, N.Y.), 3(6), 329-341 (2004-03-03)
Aryl 1-chlorovinyl sulfoxides were easily synthesized from ketones and aldehydes with aryl chloromethyl sulfoxide in three-steps with high overall yields. Low-temperature treatment of the aryl 1-chlorovinyl sulfoxides with alkyllithium or a Grignard reagent gave alkylidene carbenoids via a sulfoxide-metal exchange
M. Hojo et al.
Synthesis, 789-789 (1977)
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