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Merck
CN

254517

原戊酸三甲酯

97%

别名:

1,1,1-三甲氧基戊烷

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关于此项目

线性分子式:
CH3CH2CH2CH2C(OCH3)3
化学文摘社编号:
13820-09-2
分子量:
162.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24855389
EC Number:
237-496-5
Beilstein/REAXYS Number:
1739200
MDL number:
MFCD00008481

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产品名称

原戊酸三甲酯, 97%

InChI key

XUXVVQKJULMMKX-UHFFFAOYSA-N

InChI

1S/C8H18O3/c1-5-6-7-8(9-2,10-3)11-4/h5-7H2,1-4H3

SMILES string

CCCCC(OC)(OC)OC

assay

97%

refractive index

n20/D 1.410 (lit.)

bp

164-166 °C (lit.)

density

0.941 g/mL at 25 °C (lit.)

functional group

ether

Quality Level

200

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相关类别

Application

Trimethyl orthovalerate has been used in the preparation of:
  • various 9-O-acyl derivatives of N-acetyl- and N-glycoloyl-neuraminic acid
  • 2-methyl, 2-ethyl, 2-propyl and 2-butyl-3-benzimidazolyl-4(3H)-quinazolinones

General description

Kinetics of unimolecular gas-phase elimination of trimethyl orthovalerate has been investigated.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

107.6 °F - closed cup

flash_point_c

42 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

Lot/Batch Number
07027DE
BCBJ7637V
BCBL7467V
WXBB6914V
BCBK5581V

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Edgar Marquez et al.
The journal of physical chemistry. A, 114(12), 4203-4209 (2010-03-10)
The rates of gas-phase elimination of trimethyl orthovalerate and trimethyl orthochloroacetate have been determined in a static system, and the reaction Pyrex vessels have been deactivated with the product of decomposition of allyl bromide. The reactions are unimolecular and follow
A facile synthesis of new 3-(2-benzimidazolyl)-2-alkyl-4-(3H)-quinazolinones under microwave irradiation.
Hazarkhani H and Karimi B.
Tetrahedron, 59(26), 4757-4760 (2003)
H Ogura et al.
Carbohydrate research, 167, 77-86 (1987-09-15)
Various 9-O-acyl derivatives of N-acetyl- and N-glycoloyl-neuraminic acid, and O-(5-acetamido-3,5-dideoxy-D-glycero-alpha- and beta-D-galacto-2-nonulopyranosylonic acid)-(2----6)-O-beta-D-galactopyranosyl-(1----4)-D-glucopyranose were regioselectively synthesized by use of ortho esters. In addition, 5-acetamido-4-O-acetyl-D-glycero-D-galacto-2-nonulopyranosonic acid was prepared starting from the benzyl and methyl esters of N-acetylneuraminic acid.

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