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Merck
CN

255068

三(甲基硫代)甲烷

98%

别名:

三(甲硫基)甲烷

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关于此项目

线性分子式:
(CH3S)3CH
化学文摘社编号:
5418-86-0
分子量:
154.32
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24855282
MDL number:
MFCD00009851
Beilstein/REAXYS Number:
1733825
Assay:
98%

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InChI

1S/C4H10S3/c1-5-4(6-2)7-3/h4H,1-3H3

SMILES string

CSC(SC)SC

InChI key

YFMZQCCTZUJXEB-UHFFFAOYSA-N

assay

98%

Quality Level

100

bp

102 °C/15 mmHg (lit.), 225-227 °C (lit.)

mp

16 °C (lit.)

density

1.16 g/mL at 25 °C (lit.)

functional group

thioether

相关类别

General description

Tris(methylthio)methane is a carboxylic anion equivalent.

Application

Tris(methylthio)methane has been used in synthesis of:
  • (−)-nephrosteranic acid and (−)-roccellaric acid
  • (4R,5R)-5-({[1-(tert-butyl)-1,1-diphenylsilyl]oxy}methyl)4-[tri(methylthio)methyl]tetrahydro-furan-2-one
  • terminal difluoromethylenes

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

186.8 °F - closed cup

flash_point_c

86 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
33297LJ
11313TG
09614LS
08319HR
08117BW

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Claudia Mugnaini et al.
Bioorganic & medicinal chemistry, 11(3), 357-366 (2003-01-09)
Novel nucleoside analogues of both D and L enantiomeric series were prepared by coupling reaction between a 2',3'-dideoxy-3'-modified furanose moiety and four different nucleobases. Though in all cases anomeric mixtures of nucleosides were obtained, the presence of the sterically bulky
From ketones, aldehydes or alkyl halides to terminal 1, 1-difluoroolefins using BrF3.
Hagooly A and Rozen S.
Journal of Fluorine Chemistry, 126(8), 1239-1245 (2005)
Bin Mao et al.
Organic letters, 13(5), 948-951 (2011-01-28)
An efficient catalytic asymmetric synthesis of chiral γ-butenolides was developed based on the hetero-allylic asymmetric alkylation (h-AAA) in combination with ring closing metathesis (RCM). The synthetic potential of the h-AAA-RCM protocol was illustrated with the facile synthesis of (-)-whiskey lactone

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