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Merck
CN

255335

2-噻酚磺酰氯

96%

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关于此项目

经验公式(希尔记法):
C4H3ClO2S2
化学文摘社编号:
分子量:
182.65
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
240-677-1
Beilstein/REAXYS Number:
123536
MDL number:
Assay:
96%
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assay

96%

bp

130-132 °C/14 mmHg (lit.)

mp

30-32 °C (lit.)

SMILES string

ClS(=O)(=O)c1cccs1

InChI

1S/C4H3ClO2S2/c5-9(6,7)4-2-1-3-8-4/h1-3H

InChI key

VNNLHYZDXIBHKZ-UHFFFAOYSA-N

General description

Kinetics of reactions of 2-thiophenesulfonyl chloride with substituted anilines in methanol has been reported. Kinetics of solvolysis of 2-thiophenesulfonyl chloride in binary solvent mixtures has been studied.

Application

2-Thiophenesulfonyl chloride has been used in the preparation of 2-((trans-2-phenyl cyclopropyl)sulfonyl)thiophene.


pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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2-(trans-. beta.-Styrylsulfonyl)-and 2-((trans-2-phenylcyclopropyl) sulfonyl) thiophene.
Goralski CT.
The Journal of Organic Chemistry, 37(14), 2354-2355 (1972)
Reaction kinetics of 3-thiophenesulfonyl chloride with anilines in methanol.
Arcoria A, et al.
The Journal of Organic Chemistry, 39(12), 1689-1691 (1974)
Malcolm J D'Souza et al.
International journal of molecular sciences, 9(5), 914-925 (2009-03-28)
Specific rates of solvolysis in hydroxylic solvents available for the solvolysis of 2-thiophenesulfonyl chloride and phenylmethanesulfonyl chloride are supplemented by determining the values in fluoroalcohol-containing solvents. The data sets are then correlated using the extended Grunwald-Winstein equation. For both substrates



全球贸易项目编号

货号GTIN
255335-25G04061833045619
255335-1G04061826015285
255335-5G04061826015292