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255661

亚乙基丙二酸二甲酯

98%

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线性分子式:
CH3CH=C(CO2CH3)2
化学文摘社编号:
17041-60-0
分子量:
158.15
UNSPSC Code:
12352100
PubChem Substance ID:
24855472
MDL number:
MFCD00008447
Assay:
98%
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assay

98%

refractive index

n20/D 1.447 (lit.)

density

1.111 g/mL at 25 °C (lit.)

SMILES string

COC(=O)\C(=C\C)C(=O)OC

InChI

1S/C7H10O4/c1-4-5(6(8)10-2)7(9)11-3/h4H,1-3H3

InChI key

FRCFZWCJSXQAMQ-UHFFFAOYSA-N

General description

Palladium (0)-catalyzed deconjugative allylation of dimethyl ethylidenemalonate has been reported.

Application

Dimethyl ethylidenemalonate has been employed:
  • as electrophile in catalytic asymmetric Michael reactions of enamides and enecarbamates
  • in preparation of N-bound α-cyanocarbanion complexes

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

206.6 °F - closed cup

flash_point_c

97.00 °C - closed cup

ppe

Eyeshields, Gloves

法规信息

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分析证书(COA)

Lot/Batch Number
01102BE
S33818
12515LD
09222TC
12403HF

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Yoshihiro Sato et al.
The Journal of organic chemistry, 68(25), 9858-9860 (2003-12-06)
Palladium(0)-catalyzed deconjugative allylation of alkenylidenemalonates and alkylidenemalonates was achieved for the first time. Reactions of dimethyl 2-((E)-but-2-enylidene)malonate with various allylic acetates using LHMDS as a base in DMF in the presence of Pd(2)dba(3) (2.5 mol %) and PPh(3) (10 mol
Catalytic asymmetric Michael reactions with enamides as nucleophiles.
Florian Berthiol et al.
Angewandte Chemie (International ed. in English), 46(41), 7803-7805 (2007-09-05)
Carbon-carbon bond forming reactions of N-bound transition metal a-cyanocarbanions: a mechanistic probe for catalytic Michael reactions of nitriles
Naota T, et al.
Chemical Communications (Cambridge, England), 1, 63-64 (2001)

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货号GTIN
255661-5G04061837498343