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Merck
CN

260924

双(环戊二烯)二氯化铌(IV)

95%

别名:

二(环戊二烯基)二氯化铌(IV), 二氯二茂铌

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关于此项目

经验公式(希尔记法):
C10H10Cl2Nb
化学文摘社编号:
分子量:
294.00
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
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InChI

1S/2C5H5.2ClH.Nb/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

SMILES string

Cl[Nb]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI key

CYMWZQTUXXEBCR-UHFFFAOYSA-L

assay

95%

reaction suitability

core: niobium, reagent type: catalyst

Application

Catalyst for:
  • Chain growth in controlled polymerization reactions
  • Reduction elimination reactions
  • Olefin polymerization reactions

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

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分析证书(COA)

Lot/Batch Number

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M M Harding et al.
Journal of medicinal chemistry, 39(25), 5012-5016 (1996-12-06)
The solution chemistry and interactions of niobocene dichloride, Cp2NbCl2, with nucleosides, nucleotides, and amino acids has been studied by 1H and 31P NMR spectroscopy. The 1H NMR spectrum of Cp2NbCl2 in 10% DMSO-d6/D2O contains two sharp singlets consistent with hydrolysis
G Mokdsi et al.
Journal of inorganic biochemistry, 86(2-3), 611-616 (2001-09-22)
The interaction of the antitumor active metallocene dihalides Cp(2)MCl(2) (M=Ti, Nb, Mo) and 1 equiv. of glutathione was studied by (1)H NMR spectroscopy at pD 2-7 in 4 mM NaCl solutions. No interaction between glutathione and titanocene dichloride was detected

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